▎ 摘　　要

NOVELTY - 4-hydroxyquinoline carboxylate-graphene oxide cement-based permeable crystalline water-repellent material comprises composite concrete admixture, a living anion catalyst, cement, fine aggregate, rubber powder, and coupling agent, iron oxide, calcium oxide, magnesium oxide, where mass portion of the composite concrete admixture is 0.01-10, mass portion of the active anion catalyst is 0.01-10, the mass portion of the fine aggregate is 0.1-10, and the mass portion of the rubber powder is 1-15, the mass ratio of the coupling agent is 0.01-1, the total mass portion of iron oxide, calcium oxide, magnesium oxide is 0.1-15, the other is cement, and the living anion catalyst is 4-hydroxyquinoline carboxylate-graphite oxide. The olefinic composite concrete admixture comprising early strength agent, a quick setting agent, an air entraining agent, a water reducing agent and a condensing agent. USE - 4-hydroxyquinoline carboxylate-graphene oxide cement-based permeable crystalline water-repellent material. ADVANTAGE - The 4-hydroxyquinoline carboxylate-graphene oxide cement-based permeable crystalline water-repellent material which improves compactness of the baseconcrete water-proof material, reduces baseconcrete moisture effects, capillary action, chemicalerosion, permeation and freeze-thaw cycle such asthe damage of the building and increases durability of the concrete and has good waterproofperformance. DETAILED DESCRIPTION - The early strengthening agent is a chloride, a carbonate, a nitrate, a thiosulfate or a silicate, condensate of aluminate, alkaline hydroxide, triethanolamine, calcium formate, calcium acetate, calcium propionate and calcium butyrate, urea, oxalic acid, amine and formaldehyde, and the air entraining agent is wood resin salt, synthetic detergent, lignosulfonate, protein salt, fat resin acid and the salt, water reducing agent is one of NC, ESJ, lignosulfonate, methylnaphthalenesulfonate condensate, polyalkylarylsulfonate condensate, retarder is sodium potassium tartrate, fluorosilicate, ferrous sulfate, phosphoric acid, sodium sulfite, lactic acid, calcium tartaric acid gluconate, sodium lignosulfonate, calcium lignosulfonate, magnesium lignosulfonate, cement is high alumina cement or portland cement, the fine aggregate is quartz sand, silica powder or natural river sand, and the coupling agent is a silane coupling agent. The 4-hydroxyquinoline carboxylate-graphene oxide cement-based permeable crystalline waterproof material, where composite concrete admixture has a mass fraction of 0.1 to 10 is active. The mass fraction of the anion catalyst is 0.1-8, the mass fraction of the fine aggregate is 0.1-7, the mass fraction of the rubber powder is 1-10, the mass fraction of the coupling agent is 0.01-0.5, and the total mass of Fe2O3, CaO, MgO serving size is 1-12. An INDEPENDENT CLAIM is included for a method for preparing a 4-hydroxyquinoline carboxylate-graphene oxide cement-based permeable crystalline waterproof material, which involves weighing each component in proportion mixture is uniformly stirred in a gravity-free mortar mixer to obtain final product.