• 专利标题:   Synthesizing polyaniline/reduced graphene/polypyrrole material comprises e. g. dissolving graphene and pyrrole in deionized water, sonicating, adding ferric chloride hexahydrate, stirring and washing with ethanol and deionized water.
  • 专利号:   CN108841173-A
  • 发明人:   LIU Q, ZHANG G
  • 专利权人:   UNIV NANCHANG HANGKONG
  • 国际专利分类:   C08L079/02, C08L079/04, C08K003/04, C08K005/42, C08G073/02, C08G073/06, H01M004/86, H01M004/88, H01M008/16
  • 专利详细信息:   CN108841173-A 20 Nov 2018 C08L-079/02 201902 Pages: 5 Chinese
  • 申请详细信息:   CN108841173-A CN10489123 21 May 2018
  • 优先权号:   CN10489123

▎ 摘  要

NOVELTY - Synthesizing polyaniline/reduced graphene/polypyrrole material comprises (i) dissolving graphene and pyrrole in deionized water, sonicating, adding ferric chloride hexahydrate and stirring, washing with ethanol and deionized water, and drying to obtain graphene/polypyrrole; and (ii) purifying analytical pure aniline by distillation at 180 degrees C, dissolving the aniline in a hydrochloric acid solution and sodium dodecyl benzene sulfonate, dissolving graphene/polypyrrole and ammonium persulfate in hydrochloric acid solution, dropping the aniline acidic solution into the ammonium persulfate solution, reacting at room temperature for 12 hours, filtering the reaction solution, and washing the retentate with ethanol and deionized water, drying to obtain polyaniline/graphene/polypyrrole powder, adding sodium borohydride solution into ethanol, reacting, filtering the reaction solution, washing the retentate with ethanol and deionized water and drying. USE - The method is useful for synthesizing polyaniline/reduced graphene/polypyrrole material. DETAILED DESCRIPTION - Synthesizing polyaniline/reduced graphene/polypyrrole material comprises (i) dissolving graphene and pyrrole in deionized water, sonicating for 1 hour, adding ferric chloride hexahydrate, and stirring for 5 hours, washing with ethanol and deionized water, and drying at 60 degrees C to obtain graphene/polypyrrole; and (ii) purifying analytical pure aniline by distillation at 180 degrees C, dissolving the aniline in a hydrochloric acid solution and sodium dodecyl benzene sulfonate, dissolving graphene/polypyrrole and ammonium persulfate in hydrochloric acid solution, dropping the aniline acidic solution into the ammonium persulfate solution, reacting at room temperature for 12 hours, filtering the reaction solution, and washing the retentate with ethanol and deionized water, drying in a 50 degrees C dry box to obtain polyaniline/graphene/polypyrrole powder, adding sodium borohydride solution into ethanol, and reacting at room temperature for 12 hours, filtering the reaction solution, washing the retentate with ethanol and deionized water and drying in a vacuum oven at 50 degrees C. An INDEPENDENT CLAIM is also included for preparing polyaniline/reduced graphene/polypyrrole cathode microbial fuel battery, comprising (a) mixing the synthesized polyaniline/reduced graphene/polypyrrole material and binder on 2/asterisk1 cm carbon cloth, and assembling the mixture into cathode chamber of the microbial fuel cell; and (b) adopting the microbial fuel cell for double-chamber structure, separating the two chambers are by a proton exchange membrane, placing the configured acidic potassium dichromate and the anode microbial growth solution separately in the corresponding anion and anode chambers for cultivation.