• 专利标题:   Method for preparing graphene modified bismaleimide resin composite material that is utilized in e.g. civil field, involves vacuumizing mixture to remove solvent, and heating mixture for performing addition reaction to resin base.
  • 专利号:   CN102352038-A, CN102352038-B
  • 发明人:   QIU J, WANG Z
  • 专利权人:   UNIV TONGJI
  • 国际专利分类:   C08G073/10
  • 专利详细信息:   CN102352038-A 15 Feb 2012 C08G-073/10 201230 Pages: 9 Chinese
  • 申请详细信息:   CN102352038-A CN10204405 21 Jul 2011
  • 优先权号:   CN10204405

▎ 摘  要

NOVELTY - A graphene modified bismaleimide resin composite material preparing method involves filtering, washing and drying mixture of acylated graphene and diamine or polyamine to obtain a surface with active amino graphene. 1 weight parts of the graphene and 1-1000 weight parts of organic solvent are mixed and stirred. Amination of the graphene is dispersed in the solvent. 1-1000 weight parts of bismaleimide is added to solution at 25-100 degrees C and vacuumized for 100 hours to remove the solvent. The mixture is heated for performing addition reaction to a resin base to obtain a composite material. USE - Method for preparing a graphene modified bismaleimide resin composite material. Uses include but are not limited to aerospace, automobile ship, transport and communication trade fields and electronic and civil fields. ADVANTAGE - The method enables utilizing aminated strength and toughness of the graphene bismaleimide, improving a plane with bonding strength of matrix resin and performanceof the graphene modified bismaleimide resin nano composite material and ensuring convenient graphite alkene in industrial application. DETAILED DESCRIPTION - A graphene modified bismaleimide resin composite material preparing method involves mixing 1 weight part of dry graphene and 10-1000 weight parts of inorganic acids in 1-100 kHz ultrasonic or 10x 106 revolution/minute, and stirred for 1-100 hours. The mixture is heated at 30-120 degrees C, reacted for 1-100 hours and filtered by a micro-filtration membrane. The mixture is repeatedly washed till a filtrate is neutral and dried in vacuum for 48 hours at 45-200 degrees C to obtain a purified graphite alkene. 1 weight part of the graphite alkene and 10-1000 weight parts of strong oxidizing acid are mixed in 1-100 kHz ultrasonic for 1 minute-100 hours, heated at 30-100 degrees C and stirred for 0.5-100 hours. The mixture is filtered by a microporous filtering film and repeatedly washed till the filtrate is neutral. The mixture is dried at 30-200 degrees C in vacuum for 48 hours to obtain graphene. 1 weight part of the graphite and 1-200 weight parts of an acylating agent are mixed in 1-100 kHz ultrasonic for 0.5-10 hours, heated at 40-200 degrees C and stirred for 0.5-120 hours. The mixture is filtered and repeatedly washed to remove an acylating reagent to obtain acylated graphene. 1 weight part of the acylated graphene and 1-1000 weight parts of diamine or polyamine are mixed for 1-100 kHz ultrasonic for 1 minutes-100 hours and reacted for 1-100 hours at 45-200 degrees C. The mixture is filtered and repeatedly washed for 48 hours at 200 degrees C and dried for 0.5-48 hours in vacuum to obtain a surface with active amino graphene. 1 weight parts of the amino graphene and 1-1000 weight parts of organic solvent are mixed and stirred in 1-120 kHz ultrasonic for 10x 106 revolution/minute and 1 minute-100 hours. Amination of the graphene is uniformly dispersed in the organic solvent. 1-1000 weight parts of bismaleimide is added to solution at 25-100 degrees C and vacuumized 100 hours to remove the organic solvent. The mixture is heated for performing addition reaction to a resin base to obtain a graphene modified bismaleimide resin nano composite material. DESCRIPTION OF DRAWING(S) - The drawing shows a graphical representation of a graphene modified bismaleimide resin composite material preparation method.'(Drawing includes non-English language text)'