• 专利标题:   Preparing ultra-high wear-resistant graphene epoxy resin composite material involves adding curing accelerator to epoxy resin solution, and then placing under stirring to obtain mixed solution A.
  • 专利号:   CN112226043-A, US2022112353-A1
  • 发明人:   ZHANG Z, DU Y, LIU D, GUO L
  • 专利权人:   UNIV DALIAN TECHNOLOGY, UNIV DALIAN TECHNOLOGY
  • 国际专利分类:   C08J003/205, C08K003/04, C08L063/00
  • 专利详细信息:   CN112226043-A 15 Jan 2021 C08L-063/00 202120 Pages: 6 Chinese
  • 申请详细信息:   CN112226043-A CN11093884 14 Oct 2020
  • 优先权号:   CN11093884

▎ 摘  要

NOVELTY - Preparing ultra-high wear-resistant graphene epoxy resin composite material involves adding curing accelerator to the epoxy resin solution in a mass ratio of 1:1000-5:1000, and then placing at 70-90 degrees C under stirring for 6-10 hours to obtain mixed solution A. The curing agent is added to the mixed solution A to obtain mixed solution B. The graphene powder is added to the mixed solution B to obtain a mixed solution C. The mixed solution C is poured into the mold and placed in a vacuum at 45-70 degrees C for degassing to remove bubbles for 2-6 hours. The mixed solution C is placed at 110-145 degrees C for 2-4 hours to a soft gel state under normal pressure, and then placed at 145-180 degrees C for 10-16 hours to obtain ultra-high wear-resistant graphene epoxy resin composite material. The graphene powder is a mixture of graphene, graphene oxide, and reduced graphene oxide powder. USE - Method for preparing ultra-high wear-resistant graphene epoxy resin composite material. ADVANTAGE - The method prepares the ultra-high wear-resistant graphene epoxy resin composite material in a simple, cost-effective and eco-friendly manner with improved friction and wear performance. DETAILED DESCRIPTION - Preparing ultra-high wear-resistant graphene epoxy resin composite material involves adding curing accelerator to the epoxy resin solution in a mass ratio of 1:1000-5:1000, and then placing at 70-90 degrees C under stirring for 6-10 hours to obtain mixed solution A. The curing agent is added to the mixed solution A to obtain mixed solution B. The graphene powder is added to the mixed solution B to obtain a mixed solution C. The mixed solution C is poured into the mold and placed in a vacuum at 45-70 degrees C for degassing to remove bubbles for 2-6 hours. The mixed solution C is placed at 110-145 degrees C for 2-4 hours to a soft gel state under normal pressure, and then placed at 145-180 degrees C for 10-16 hours to obtain ultra-high wear-resistant graphene epoxy resin composite material. The graphene powder is a mixture of graphene, graphene oxide, and reduced graphene oxide powder. The epoxy resin is a mixture of bisphenol A type epoxy resin, bisphenol F type epoxy resin, polyphenol type glycidyl ether epoxy resin, and glycidyl ester type epoxy resin. The curing agent is a heating curing type acid anhydride curing agent. The curing accelerator is a mixture of tertiary amines and their derivatives, quaternary ammonium salts, and metal acetylacetone salts.