• 专利标题:   Graphene oxide flake multi-walled carbon nanotube-synergistically enhanced polypropylene resin includes liquid propylene, multi-walled carbon nanotube-supported titanium-zirconium catalyst, liquid ethylene and triethylaluminum.
  • 专利号:   CN104987453-A
  • 发明人:   WU C
  • 专利权人:   HEFEI LANKE NEW MATERIAL CO LTD
  • 国际专利分类:   C08F210/06, C08F210/16, C08F004/02, C08F004/646, C08K003/04, C08K007/24, C08K009/06
  • 专利详细信息:   CN104987453-A 21 Oct 2015 C08F-210/16 201609 Pages: 5 Chinese
  • 申请详细信息:   CN104987453-A CN10354358 25 Jun 2015
  • 优先权号:   CN10354358

▎ 摘  要

NOVELTY - Graphene oxide flake multi-walled carbon nanotube-synergistically enhanced polypropylene resin comprises 350-380 pts. wt. liquid propylene, 2.5-3.5 pts. wt. multi-walled carbon nanotube-supported titanium-zirconium catalyst, 90-100 pts. wt. liquid ethylene, 7-9 pts. wt. triethylaluminum, 5.4-6.2 pts. wt. diphenyl dimethoxysilane, 1.8-2.2 pts. wt. ether diamine, 1.5-1.9 pts. wt. ether dianhydride, 50-60 pts. wt. n-heptane, hydrogen, 0.1-0.2 pt. wt. ammonium hexafluorosilicate, 15-20 pts. wt. octene, 0.1-0.2 pt. wt. aminopropyltriethoxysilane and 1.2-1.8 pts. wt. graphene oxide flakes. USE - Graphene oxide flake multi-walled carbon nanotube-synergistically enhanced polypropylene resin. ADVANTAGE - The resin has high strength, modulus, impact toughness and rigidity, enhanced high temperature properties and improved dispersion. DETAILED DESCRIPTION - Graphene oxide flake multi-walled carbon nanotube-synergistically enhanced polypropylene resin comprises 350-380 pts. wt. liquid propylene, 2.5-3.5 pts. wt. multi-walled carbon nanotube-supported titanium-zirconium catalyst, 90-100 pts. wt. liquid ethylene, 7-9 pts. wt. triethylaluminum, 5.4-6.2 pts. wt. diphenyl dimethoxysilane, 1.8-2.2 pts. wt. ether diamine, 1.5-1.9 pts. wt. ether dianhydride, 50-60 pts. wt. n-heptane, hydrogen, 0.1-0.2 pt. wt. ammonium hexafluorosilicate, 15-20 pts. wt. octene, 0.1-0.2 pt. wt. aminopropyltriethoxysilane, 1.2-1.8 pts. wt. graphene oxide flakes and 8-12 pts. wt. water. An INDEPENDENT CLAIM is included for preparation of graphene oxide flake multi-walled carbon nanotube-synergistically enhanced polypropylene resin comprises mixing aminopropyltriethoxysilane and water, adding multi-walled carbon nanotube-supported titanium-zirconium catalyst, heating at 60-70 degrees C, reacting for 20-30 minutes, adding graphene oxide sheets, stirring for 10-15 minutes, drying, adding propylene, triethylaluminum, catalyst and diphenyl dimethoxysilane, mixing, passing through hydrogen at 50-80 degrees C, polymerizing for 7-9 hours, adding ethylene and 1-octene, reacting for 7-9 hours, autoclaving with propylene gas, adding remaining propylene, triethylaluminum, diphenyl dimethoxysilane and n-heptane, stirring, adding catalyst, heating to 50-80 degrees C, reacting for 5-8 hours, cooling, adding remaining raw materials, heating to 50-80 degrees C, reacting for 8-10 hours, venting and vacuum drying.