• 专利标题:   Preparation of reduction-oxidation graphene modified nickel-cobalt-manganese ternary anode material by dispersing nickel-cobalt-manganese ternary anode material in solvent, dropping ammonia water solution, and adding surface modifier.
  • 专利号:   CN113328075-A
  • 发明人:   SONG H, ZHAO D
  • 专利权人:   UNIV BEIJING CHEM TECHNOLOGY
  • 国际专利分类:   C01B032/198, H01M010/0525, H01M004/36, H01M004/485, H01M004/505, H01M004/525, H01M004/62
  • 专利详细信息:   CN113328075-A 31 Aug 2021 H01M-004/36 202190 Pages: 6 Chinese
  • 申请详细信息:   CN113328075-A CN10583578 27 May 2021
  • 优先权号:   CN10583578

▎ 摘  要

NOVELTY - Preparation of reduction-oxidation graphene modified nickel-cobalt-manganese ternary anode material comprises dispersing nickel-cobalt-manganese ternary anode material in solvent to obtain raw material dispersion liquid, dropping ammonia water solution to make the pH alkaline, adding surface modifier, stirring, filtering, and drying to obtain surface modified nickel-cobalt-manganese ternary anode material; dispersing the surface-modified nickel-cobalt-manganese ternary anode material in a small amount of solvent to obtain dispersion liquid, dropping graphene oxide (GO) solution, stirring, filtering, and drying to obtain graphene oxide coated nickel-cobalt-manganese ternary anode material; and subjecting the graphene oxide coated nickel-cobalt-manganese ternary anode material to heat treatment reduction to obtain reduced graphene oxide (rGO) coated nickel-cobalt-manganese ternary anode material. USE - The method is for preparation of reduced graphene oxide-modified nickel-cobalt-manganese ternary anode material. ADVANTAGE - The reduced graphene oxide obtained by the heat treatment reduction has high electron conductivity and stable chemical property, contains a large amount of defects, can make Li+ ion pass through the plane of graphene, and provides high capacity and good circularity. The design of the coating structure enables to obtain anode material with high capacity and excellent cycle performance.