• 专利标题:   Photocatalytic reduction of carbon dioxide involves treating sodium hydroxide solution saturated with gaseous carbon dioxide, with modified titanium dioxide photocatalyst formed by rubbing anatase-type titanium dioxide powder with reduced graphene oxide, hydrothermally treating, and annealing.
  • 专利号:   PL434479-A1
  • 发明人:   MORAWSKI A W, KUSIAKNEJMAN E, WANAG A M, NARKIEWICZ U, KOCI K, EDELMANOVA M
  • 专利权人:   UNIV ZACHODNIOPOMORSKI TECHNOLOGICZNY
  • 国际专利分类:   B01J021/06, B01J021/18, C01G023/047
  • 专利详细信息:   PL434479-A1 27 Dec 2021 B01J-021/06 202265 Pages: 1
  • 申请详细信息:   PL434479-A1 PL434479 26 Jun 2020
  • 优先权号:   PL434479

▎ 摘  要

NOVELTY - Photocatalytic reduction of carbon dioxide involves treating an alkaline aqueous solution saturated with gaseous carbon dioxide, with 1 g/dm3 photocatalyst. The alkaline aqueous solution is sodium hydroxide with a concentration of 0.2 M. The photocatalyst is a modified titanium dioxide photocatalyst obtained by rubbing a titanium dioxide powder with the reduced graphene oxide, subjecting the composite to hydrothermal treatment at 180 degrees C in an autoclave in the presence of 2-propanol for 4 hours under pressure and then for 1 hour at the same temperature and atmospheric pressure, and annealing the composite under an inert gas atmosphere at 300-1000 degrees C for 4 hours. The titanium dioxide powder is an industrial anatase-type titanium dioxide having specific surface area of 300 m2/g or more and a particle size of up to 400 nm. The reduced graphene oxide is commercial reduced graphene oxide in the form of flakes. The inert gas atmosphere contains argon, helium and/or nitrogen. USE - Photocatalytic reduction of carbon dioxide. DETAILED DESCRIPTION - Photocatalytic reduction of carbon dioxide involves treating an alkaline aqueous solution saturated with gaseous carbon dioxide, with 1 g/dm3 photocatalyst. The alkaline aqueous solution is sodium hydroxide with a concentration of 0.2 M. The photocatalyst is a modified titanium dioxide photocatalyst obtained by rubbing a titanium dioxide powder with the reduced graphene oxide, subjecting the composite to hydrothermal treatment at 180 degrees C in an autoclave in the presence of 2-propanol for 4 hours under pressure and then for 1 hour at the same temperature and atmospheric pressure, and annealing the composite under an inert gas atmosphere at 300-1000 degrees C for 4 hours. The titanium dioxide powder is an industrial anatase-type titanium dioxide having specific surface area of 300 m2/g or more and a particle size of up to 400 nm. The reduced graphene oxide is commercial reduced graphene oxide in the form of flakes. The inert gas atmosphere contains argon, helium and/or nitrogen. The mass ratio of titanium dioxide to reduced graphene oxide is 1:0.1 and titanium dioxide to 2-propanol is 1:0.8.