• 专利标题:   Synthesizing unsaturated polyester nano hybrid resin for preparing fiber reinforced material, and molding plastic or paint, involves dispersing graphene oxide powder in diol to obtain uniformly dispersed oxidized graphene/diol.
  • 专利号:   CN106750215-A, CN106750215-B
  • 发明人:   LIU C, ZHOU Y, HU L, ZHANG M, YANG X, HU Y
  • 专利权人:   INST CHEM IND FOREST PROD CHINESE ACAD
  • 国际专利分类:   C08G063/48, C08G063/49, C08G063/52, C08G063/78, C08K003/04, C09D167/06, C09D167/08, C09D007/12
  • 专利详细信息:   CN106750215-A 31 May 2017 C08G-063/52 201745 Pages: 9 Chinese
  • 申请详细信息:   CN106750215-A CN11189651 21 Dec 2016
  • 优先权号:   CN11189651

▎ 摘  要

NOVELTY - Synthesizing unsaturated polyester nano hybrid resin involves dispersing graphene oxide powder in diol to obtain uniformly dispersed oxidized graphene/ diol nano-dispersion. The unsaturated and saturated dibasic acid or dibasic acid anhydride mixture, and polymerization inhibitor are mixed, and heated at 180-220 degrees C to carried out in situ polycondensation reaction, where molar ratio of unsaturated to saturated acid or dibasic anhydride is 1:3-3:1, and molar ratio of diol, unsaturated, and saturated dibasic acid or dibasic anhydride is 1:1-1.2:1. USE - Method for synthesizing unsaturated polyester nano hybrid resin used for preparing fiber reinforced material, and molding plastic or paint (claimed). ADVANTAGE - The method enables to synthesize unsaturated polyester nano hybrid resin which has good comprehensive performance and degradable. DETAILED DESCRIPTION - Synthesizing unsaturated polyester nano hybrid resin involves dispersing graphene oxide powder in diol to obtain uniformly dispersed oxidized graphene/ diol nano-dispersion. The unsaturated and saturated dibasic acid or dibasic acid anhydride mixture, and polymerization inhibitor are mixed, and heated at 180-220 degrees C to carried out in situ polycondensation reaction, where molar ratio of unsaturated to saturated acid or dibasic anhydride is 1:3-3:1, and molar ratio of diol, unsaturated, and saturated dibasic acid or dibasic anhydride is 1:1-1.2:1. The acidity of reaction system is reduced to 70-120 milligram potassium hydroxide/gram, cooled reaction system at 120-180 degrees C, added tung oil, heated at 180-220 degrees C to continued reaction until acid value reached to 30-35 milligram potassium hydroxide/gram, reduced temperature to 100-150 degrees C, added styrene to diluted, and dispersed uniformly to obtain resin product.