• 专利标题:   Preparing polyurea/two-dimensional material/alumina super-assembly function film useful in constructing nano-channel film material, comprises e.g. preparing dispersion liquid of carboxylated graphene oxide, using vacuum filtration method to grow GO on the AAO substrate and drying.
  • 专利号:   CN114316318-A
  • 发明人:   ZENG J, HE Y, XIE L, ZHOU S, KONG B
  • 专利权人:   UNIV FUDAN
  • 国际专利分类:   C08J005/18, C08K003/04, C08K003/22, C08L075/02
  • 专利详细信息:   CN114316318-A 12 Apr 2022 C08J-005/18 202257 Chinese
  • 申请详细信息:   CN114316318-A CN11635728 29 Dec 2021
  • 优先权号:   CN11635728

▎ 摘  要

NOVELTY - Preparing polyurea/two-dimensional material/alumina super-assembly function film comprises (i) preparing a dispersion liquid of carboxylated graphene oxide, (2) using vacuum filtration method to grow GO on the AAO substrate with the assistance of interface super-assembly, (iii) drying the filtered GO/AAO composite membrane, (iv) preparing water-oil phase solution of synthetic polyurea monomer, (v) dropwise adding polyethyleneimine (PEI) onto the surface of the GO/AAO membrane and volatilizing water to dry, and (vi) adding a 2, 4-Toluene Diisocyanate (TDI) solution to the surface of GO/AAO containing a PEI polymer chain and carrying out interfacial polymerization reaction on amino groups between two phases and isocyanate in an oven to generate a compact polyurea film to obtain the product. USE - The polyurea/two-dimensional material/alumina super-assembly function film is useful in constructing nano-channel film material. ADVANTAGE - The film: can stably present in water and has excellent mechanical stability of the PGA.