• 专利标题:   Graphene paste used for cationic aqueous polyurethane paint, is aqueous dispersion containing specified amount of water and modified graphene which is formed by mixing graphene oxide aqueous dispersion and carbodiimide, and reacting.
  • 专利号:   CN107365514-A, CN107365514-B
  • 发明人:   CUI J, FENG Q, GAN L, LI J, YANG J
  • 专利权人:   UNIV SHANGHAI SCI TECHNOLOGY, SHANGHAI SC GRAPHENE IND TECHNOLOGY CO
  • 国际专利分类:   C09C001/46, C09C003/08, C09D175/04, C09D005/08
  • 专利详细信息:   CN107365514-A 21 Nov 2017 C09C-001/46 201805 Pages: 9 Chinese
  • 申请详细信息:   CN107365514-A CN10556510 10 Jul 2017
  • 优先权号:   CN10556510

▎ 摘  要

NOVELTY - A graphene paste is an aqueous dispersion formed by dispersing modified graphene in water. The ratio of modified graphene and water is 2-20 mg:1 ml. The modified graphene is obtained by adding graphene oxide into water to obtain a graphene oxide aqueous dispersion with a concentration of 1-4 mg/ml, adding carbodiimide to obtain the mixed solution by Hummers process, adjusting the pH value of the mixed solution to 10-12 with 2-5 vol.% aqueous ammonia solution, reacting at 50-90 degrees C for 5-24 hours, centrifuging or filtering, and washing the precipitate or filter cake with deionized water. USE - Graphene paste is used for cationic aqueous polyurethane paint (claimed). ADVANTAGE - The graphene paste is environmentally-friendly, and has excellent long-term storage stability of 1 year at room temperature and elastic modulus of 2.2-2.31 GPa, suppressed generation of precipitation, flocculation and gelation. The neutral spray time of 72-120 hours. DETAILED DESCRIPTION - A graphene paste is an aqueous dispersion formed by dispersing modified graphene in water. The ratio of modified graphene and water is 2-20 mg:1 ml. The modified graphene is obtained by adding graphene oxide into water to obtain a graphene oxide aqueous dispersion with a concentration of 1-4 mg/ml, adding carbodiimide to obtain the mixed solution by Hummers process, adjusting the pH value of the mixed solution to 10-12 with 2-5 vol.% aqueous ammonia solution, reacting at 50-90 degrees C for 5-24 hours, centrifuging or filtering, and washing the precipitate or filter cake with deionized water until is neutral. The carbodiimide is commercially available carbodiimide aqueous dispersion or emulsion-based carbodiimide. The weight ratio of carbodiimide and graphene oxide is 5-20:1. An INDEPENDENT CLAIM is included for usage of graphene paste in cationic aqueous polyurethane paint.