• 专利标题:   Preparing a boron-doped porous graphene cathode catalyst used as the cathode of lithium air battery, involves mixing graphene oxide powder with a solvent to obtain dispersion a, and adding template b to dispersion a to obtain dispersion c.
  • 专利号:   CN111640954-A
  • 发明人:   ZHANG J, FAN Y, SHEN S, YAN X, LUO L, WU A, ZHAO L
  • 专利权人:   UNIV SHANGHAI JIAOTONG
  • 国际专利分类:   C01B032/184, H01M012/06, H01M004/88, H01M004/96
  • 专利详细信息:   CN111640954-A 08 Sep 2020 H01M-004/88 202080 Pages: 9 Chinese
  • 申请详细信息:   CN111640954-A CN10574453 22 Jun 2020
  • 优先权号:   CN10574453

▎ 摘  要

NOVELTY - Preparing a boron-doped porous graphene cathode catalyst involves mixing graphene oxide powder with a solvent to obtain dispersion a, and adding template b to dispersion a to obtain dispersion c, and after adding hydrazine hydrate and ammonia to adjust the pH value, carrying out a solvothermal reaction, and then adding hydrogen chloride (HCl) to precipitate the mixture, filtering, washing, and drying to obtain a solid powder d. The solid powder d is heat-treated to obtain the porous reduced graphene oxide e. The heteroatomic boron precursor and the porous reduced graphene oxide are mixed uniformly, and reacted in a closed container to obtain the precursor f of the boron-doped porous graphene. The precursor f of the boron-doped porous graphene is heated in an inert gas, and obtain the boron-doped porous graphene cathode catalyst after cooling. USE - Method for preparing a boron-doped porous graphene cathode catalyst used as the cathode of lithium air battery (claimed). ADVANTAGE - The method enables to prepared a boron-doped porous graphene cathode catalyst, that has high porosity, large specific surface area and high conductivity, which is beneficial to the full diffusion of electrolyte solution and the transportation of oxygen, and with good specific capacity, electrochemical reversibility and stability, can be used as the cathode of lithium air battery.