• 专利标题:   Capturing and degrading per- or polyfluoroalkyl substance for use in aqueous film forming foam, involves capturing per- or polyfluoroalkyl substance from sample by combining sample with composite sorbent comprising metal-organic framework, and sorbing per- or polyfluoroalkyl substance to sorbent.
  • 专利号:   US2023089418-A1
  • 发明人:   MCGRAIL B P, BARPAGA D, CHATTERJEE S, MOTKURI R K
  • 专利权人:   BATTELLE MEMORIAL INST
  • 国际专利分类:   A62D003/115, A62D003/38, A62D003/40, B01J020/22, B01J027/188, B01J027/19, B01J027/195, B01J027/198, B01J031/24, B01J035/00, C02F001/28, C02F001/30, C02F001/32, C02F001/58, C02F001/72, G01N027/07, G01N027/22, G01N027/48, G01N033/18
  • 专利详细信息:   US2023089418-A1 23 Mar 2023 C02F-001/28 202330 English
  • 申请详细信息:   US2023089418-A1 US979454 02 Nov 2022
  • 优先权号:   US851854P, US979454

▎ 摘  要

NOVELTY - Method for capturing and degrading per- or polyfluoroalkyl substance (PFAS) involves: (i) capturing PFAS from a sample by combining the sample with a composite sorbent; and (ii) sorbing PFAS to the composite sorbent to form PFAS-sorbent, where the composite sorbent comprises different materials (a) and (b), (a) includes metal-organic framework (MOF), covalent organic framework, covalent organic polymer, zeolite, mesoporous silica, hierarchical porous carbon in combination with (b) of polymer, zeolite, covalent organic framework, mesoporous silica, hierarchical porous carbon, photocatalyst, carbon nanotube, graphite, graphene, graphene oxide, Prussian blue analog, and/or metal oxide. When MOF is present, MOF does not comprise zirconium-based MOF, and/or when polymer is present, then the polymer is not poly(ethylene-co-vinyl acetate). USE - Method for capturing and degrading PFAS that is used in aqueous film forming foams for fighting hydrocarbon fuel fires on military sites. ADVANTAGE - The method enables rapid, reliable, and accurate detection and quantification of PFAS in portable and field-deployable process. DETAILED DESCRIPTION - Method for capturing and degrading PFAS involves: (i) capturing PFAS from a sample by combining the sample with a composite sorbent; and (ii) sorbing the PFAS to the composite sorbent to form PFAS-sorbent, where the composite sorbent comprises different materials (a) and (b), (a) includes metal-organic framework (MOF), covalent organic framework, covalent organic polymer, zeolite, mesoporous silica, hierarchical porous carbon in combination with (b) of polymer, zeolite, covalent organic framework, mesoporous silica, hierarchical porous carbon, photocatalyst, carbon nanotube, graphite, graphene, graphene oxide, Prussian blue analog, and/or metal oxide. When MOF is present, MOF does not comprise zirconium-based MOF (Zr6O4(OH)4 and 1,4-benzodicarboxylic acid (UiO-66)), and/or when polymer is present, then the polymer is not poly(ethylene-co-vinyl acetate). DESCRIPTION OF DRAWING(S) - The drawing shows a perspective view of fluidic device. 100Fluidic device 110Upper planar substrate 120Lower planar substrate 130Thin film 140Upper sensing area