• 专利标题:   Method for improving microbial leaching of copper, involves crushing/sorting waste circuit board, obtaining metal-rich component, placing graphene-modified carbon rod electrode system in reactor, domesticating strain, and leaching.
  • 专利号:   CN105886774-A, CN105886774-B
  • 发明人:   BAI J, DENG M, GU W, LU L, WANG J, YAO H, YU W, YANG F, ZHANG C, FEI Y
  • 专利权人:   UNIV SHANGHAI SECOND POLYTECHNIC
  • 国际专利分类:   C22B015/00, C22B007/00, C25C001/12
  • 专利详细信息:   CN105886774-A 24 Aug 2016 C22B-007/00 201675 Pages: 9 Chinese
  • 申请详细信息:   CN105886774-A CN10222686 12 Apr 2016
  • 优先权号:   CN10222686

▎ 摘  要

NOVELTY - Method for improving microbial leaching of copper metal in used circuit board, involves crushing and sorting waste circuit board, obtaining metal-rich component, culturing a domestication strain, connecting a carbon rod anode and a carbon rod cathode with a copper conductor, placing obtained graphene-modified carbon rod electrode system in a reactor, domesticating strain, leaching metal-rich component, collecting leaching solution and filtering. The carbon rod anode is a conductive carbon rod. The carbon rod cathode is obtained by graphene modification of conductive carbon rod. USE - Method for improving microbial leaching of copper metal in used circuit board using graphene-modified carbon rod electrode system (claimed). ADVANTAGE - The microbial leaching of copper metal in used circuit board is economically improves by simple and environmentally-friendly process. DETAILED DESCRIPTION - Method for improving microbial leaching of copper metal in used circuit board, involves crushing and sorting waste circuit board, obtaining metal-rich component with different size, culturing a domestication strain to increase the tolerance of the strain to the copper ion, connecting a carbon rod anode and a carbon rod cathode with a copper conductor, forming a graphene-modified carbon rod electrode system, placing the carbon rod electrode system in a reactor, performing domestication of the strain, leaching metal-rich component at 25-30 degrees C and 120-150 rpm for 5-10 days, monitoring pH, divalent iron ion concentration, oxidation-reduction potential and copper leaching rate during leaching, collecting leaching solution and filtering. The area of carbon rod anode and carbon rod cathode is 0.5-10 cm2. The carbon rod anode is a conductive carbon rod. The carbon rod cathode is obtained by graphene modification of conductive carbon rod. The amount of graphene is 1-3 mg/cm2 with respect to the carbon rod cathode area.