• 专利标题:   Intumescent flame retardant comprises chitosan salt, and binary hybrid nanoparticle zeolitic imidazolate framework-8 doped graphene oxide, and chitosan salt is prepared by reacting 2-carboxyethylphenylphosphinic acid with chitosan.
  • 专利号:   CN110396284-A
  • 发明人:   WANG X, WANG K, ZHANG M, DING X, WANG M, ZHAN Y
  • 专利权人:   UNIV NANJING SCI TECHNOLOGY
  • 国际专利分类:   C08B037/08, C08K003/04, C08K009/12, C08L005/08, C08L067/04, C08L087/00
  • 专利详细信息:   CN110396284-A 01 Nov 2019 C08L-067/04 201990 Pages: 6 Chinese
  • 申请详细信息:   CN110396284-A CN10630458 12 Jul 2019
  • 优先权号:   CN10630458

▎ 摘  要

NOVELTY - Intumescent flame retardant comprises chitosan salt, and binary hybrid nanoparticle zeolitic imidazolate framework-8 doped graphene oxide (GO). The chitosan salt is prepared by reacting 2-carboxyethylphenylphosphinic acid with chitosan. USE - Used as intumescent flame retardant. ADVANTAGE - The polylactic acid material: has simple formula, and no halogen environment; obviously improves mechanical properties, and flame retardant properties of polylactic acid; obviously weakens droplets of flame-retardant polylactic acid material; forms continuous and dense carbon layer after combustion; and has heat insulating and oxygen barrier function. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) preparing intumescent flame retardant, comprising (i) dissolving 2-carboxyethylphenylphosphinic acid in water, heating at 60-70 degrees C in a water bath, stirring for completely dissolving to obtain 2 wt.% aqueous solution of 2-carboxyethylphenylphosphoric acid, adding chitosan to aqueous solution of 2-carboxyethylphenylphosphoric acid, stirring at 60-70 degrees C for 5-6 hours, cooling, precipitating, and drying to obtain chitosan salt, (ii) adding 2-methylimidazole, and zinc nitrate hexahydrate sequentially to methanol dispersion of graphene oxide to obtain ZIF-8 doped GO, and (iii) mixing chitosan salt, and ZIF-8 doped GO to obtain the product; (2) intumescent flame-retardant polylactic acid material comprising polylactic acid, and intumescent flame retardant having mass ratio of 95:5; and (3) preparing the intumescent flame-retardant polylactic acid material, comprising using solution blending method, adding chloroform solution of polylactic acid, and a chloroform dispersion of intumescent flame retardant in a mass ratio of 95:5, blending, and coating film to obtain the finished product.