• 专利标题:   Spherical nano-graphene material useful for cathode material of lithium ion battery, comprises e.g. graphene oxide, bisphenol A type diglycidyl ether, catalyst, catalytic auxiliary agent, metal oxide, and organic solvent.
  • 专利号:   CN112520728-A
  • 发明人:   CHEN R, CHEN G, YAN T, WANG S, CHEN H, LI S, HAN J, LI X, ZHAO Y
  • 专利权人:   LUOBEI RUIZHE ALKENE CARBON NEW MATERIAL CO LTD
  • 国际专利分类:   B82Y030/00, C01B032/184, C01B032/194, H01M010/0525, H01M004/133, H01M004/1393, H01M004/587
  • 专利详细信息:   CN112520728-A 19 Mar 2021 C01B-032/184 202133 Pages: 8 Chinese
  • 申请详细信息:   CN112520728-A CN11387731 01 Dec 2020
  • 优先权号:   CN11387731

▎ 摘  要

NOVELTY - Spherical nano-graphene material comprises 30-50 pts. wt. graphene oxide, 10-20 pts. wt. bisphenol A type diglycidyl ether, 15-25 pts. wt. polyvinyl pyrrolidone, 5-10 pts. wt. modifier, 1-5 pts. wt. catalyst, 2-5 pts. wt. catalytic auxiliary agent, 8-15 pts. wt. metal oxide, and 80-100 pts. wt. organic solvent. USE - The material is useful for cathode material of lithium ion battery (claimed). ADVANTAGE - The material has diameter of 1-10 nm, first discharge specific capacity of more than 1350 mAh/g, coulombic efficiency of more than 98.5%, and capacity retention rate of more than above 90% at 1C100 cycles. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing the material, comprising (i) grinding graphene oxide, mixing with modifier, and modifying to obtain modified graphene oxide; (ii) adding the catalyst, catalytic auxiliary agent and metal oxide into water for ion complexing, and spray-drying to obtain particles; (iii) dispersing modified graphene oxide and bisphenol A type diglycidyl ether in water, ultrasonically dissolving, and spray-drying to obtain spherical graphene powder; and (iv) adding particles and spherical graphene powder into organic solvent, and stirring uniformly at room temperature, adding polyvinyl pyrrolidone into organic solvent, and heating at 1200-1500 degrees C for 1-2 hours under a dual atmosphere of helium and nitrogen to completely evaporate organic solvent.