• 专利标题:   Preparing glycolic acid by electrocatalytic hydrogenation of oxalic acid comprises electrolyzing aqueous electrolyte containing oxalic acid in catalyst-containing electrode, evaporating water in electrolyte to concentrate glycolic acid content, precipitating glycolic acid crystals, filtering, drying.
  • 专利号:   CN116180109-A
  • 发明人:   LI S, GONG M
  • 专利权人:   UNIV FUDAN
  • 国际专利分类:   B82Y030/00, C25B011/091, C25B003/07, C25B003/25
  • 专利详细信息:   CN116180109-A 30 May 2023 C25B-003/07 202355 Chinese
  • 申请详细信息:   CN116180109-A CN10021639 07 Jan 2023
  • 优先权号:   CN10021639

▎ 摘  要

NOVELTY - Preparing glycolic acid by electrocatalytic hydrogenation of oxalic acid comprises (i) electrolyzing aqueous electrolyte containing oxalic acid in catalyst-containing electrode in the electrolytic cell to obtain a glycolic acid solution, and (ii) evaporating the water in the electrolyte to concentrate the glycolic acid content, and using the crystallization method to precipitate the glycolic acid crystals, filtering, separating and vacuum drying. The metal oxide in the material is lead, tin, tantalum, zirconium, niobium, vanadium, chromium, titanium, and/or hafnium oxide. The nano-carbon material used as the carrier is activated carbon, carbon black, carbon nanotubes, graphene, porous nano-carbon spheres, mesoporous carbon, and carbon nanofibers. USE - Method for preparing glycolic acid by electrocatalytic hydrogenation of oxalic acid. ADVANTAGE - The method solves the problems of high reaction temperature and high toxicity of raw materials in the existing synthesis process of glycolic acid, has non-toxic raw materials, mild reaction conditions, low equipment cost and no need to use hydrogen, and is economical.