• 专利标题:   Synthesis of lithium-rich iron-manganese-based complex cathode material in situ oxidation of graphene conductive grid useful for lithium ion batteries, comprises dispersing the graphene oxide in an amount of ethanol or water.
  • 专利号:   CN105406047-A, CN105406047-B
  • 发明人:   LV Z, WANG Y, XU T, ZHAO Y, ZHAO Z
  • 专利权人:   UNIV BEIJING TECHNOLOGY, UNIV BEIJING TECHNOLOGY
  • 国际专利分类:   H01M010/0525, H01M004/36, H01M004/505, H01M004/525, H01M004/62
  • 专利详细信息:   CN105406047-A 16 Mar 2016 H01M-004/36 201631 Pages: 11 English
  • 申请详细信息:   CN105406047-A CN11017998 29 Dec 2015
  • 优先权号:   CN11017998

▎ 摘  要

NOVELTY - Synthesis of lithium-rich iron-manganese-based complex cathode material in situ oxidation of graphene conductive grid comprises (i) dispersing the graphene oxide in an amount of ethanol or water; (ii) taking low-melting salt by lithium-rich iron-manganese-based anode material element molar ratio, heating in a water bath and stirring into a molten state; (iii) adding graphene oxide dispersion into molten salt; (iv) stirring step (iii) mechanically and evaporating; (v) transferring resultant black gel to blast oven, drying; and (vi) crushing and then treating at high temperature. USE - The synthesis of lithium-rich iron-manganese-based complex cathode material in situ oxidation of graphene conductive grid is useful for lithium ion batteries (claimed). ADVANTAGE - The synthesis of lithium-rich iron-manganese-based complex cathode material in situ oxidation of graphene conductive grid is simple, has improved the stability and is economical. DETAILED DESCRIPTION - Synthesis of lithium-rich iron-manganese-based complex cathode material in situ oxidation of graphene conductive grid comprises (i) dispersing the graphene oxide in an amount of ethanol or water, at room temperature and stirring for 2-4 hours to obtain ultrasonic graphene oxide dispersion and graphene oxide dispersion concentration at 0.1-2 mg/ml; (ii) taking low-melting salt by lithium-rich iron-manganese-based anode material element molar ratio, heating in a water bath and stirring into a molten state; (iii) adding slowly dropwise the step (i) graphene oxide dispersion into the step (ii) in the molten salt; (iv) stirring step (iii) mechanically and evaporating to black gel; (v) transferring the step (iv) resultant black gel to a blast oven, blast drying to obtain a porous fluffy black mesh material, it is the lithium-rich iron-manganese-based anode material/graphene oxide complex precursor; and (vi) crushing the step (v) obtained black mesh precursor to powder and then treating at high temperature.