• 专利标题:   Preparation of perylene anhydride non-covalently modified graphene by adding graphene in N-methylpyrrolidone, ultrasonically dispersing and adding zinc acetate and 3,4,9,10-perylene tetracarboxylic dianhydride.
  • 专利号:   CN106977880-A, CN106977880-B
  • 发明人:   XU X, ZHAO L, LI Y, GAO J, CHENG J, YE C, LU S, WEI C
  • 专利权人:   UNIV GUILIN TECHNOLOGY, UNIV GUILIN TECHNOLOGY
  • 国际专利分类:   C08G018/42, C08G018/73, C08K003/04, C08K009/04, C08L063/00, C08L075/06
  • 专利详细信息:   CN106977880-A 25 Jul 2017 C08L-063/00 201763 Pages: 6 Chinese
  • 申请详细信息:   CN106977880-A CN10219362 06 Apr 2017
  • 优先权号:   CN10219362

▎ 摘  要

NOVELTY - Preparation of perylene anhydride non-covalently modified graphene comprises adding 0.02 g graphene in 80 ml N-methylpyrrolidone, ultrasonically dispersing for 0.5-1 hour, adding 0.0037 g zinc acetate, 0.0392 g 3,4,9,10-perylene tetracarboxylic dianhydride and 0.0242 g tris(hydroxymethyl)aminomethane, continuously ultrasonically dispersing for 0.5-1 hour, reacting under nitrogen atmosphere at 180 degrees C for 10-14 hours, adding the reaction liquid into absolute ethyl alcohol, precipitating, filtering, and vacuum drying the obtained filtrate to obtain purple black product. USE - Preparation of perylene anhydride non-covalently modified graphene used in preparation of epoxy resin-based composite material and high performance shape memory polymer (all claimed). ADVANTAGE - The method is very simple and easy and fully utilizes the synergistic effect of perylene anhydride and graphene.