• 专利标题:   Preparing silicon-carbon composite particles involves providing carbon scaffold comprising pore volume, heating porous carbon scaffold, contacting carbon scaffold with silane feedstock gas, mole silicon in silicon-carbon composite is determined from silicon content in silicon-carbon composite.
  • 专利号:   US2023155112-A1
  • 发明人:   PATEL R, TIMMONS C, SAKSHAUG A J, DHANABALAN A, COSTANTINO H R
  • 专利权人:   GROUP14 TECHNOLOGIES INC
  • 国际专利分类:   C23C016/24, H01M004/36, H01M004/38, H01M004/587
  • 专利详细信息:   US2023155112-A1 18 May 2023 H01M-004/36 202344 English
  • 申请详细信息:   US2023155112-A1 US156939 19 Jan 2023
  • 优先权号:   US996694, US156939

▎ 摘  要

NOVELTY - Preparing silicon-carbon composite particles involves providing a carbon scaffold comprising a pore volume, where the pore volume comprises ≥ 70% microporosity, heating the porous carbon scaffold to a temperature from 300-500℃, contacting the carbon scaffold with a silane feedstock gas, the mole silicon in the silicon-carbon composite is determined from the silicon content in the silicon-carbon composite by thermogravimetric analysis. USE - Method for preparing silicon-carbon composite particles. ADVANTAGE - The method improves rate capability of material by allowing lithium ions to intercalate isotropically as opposed to graphite where lithiation only proceed in parallel to the stacked graphene plane and reduces surface side reactions. DETAILED DESCRIPTION - Preparing silicon-carbon composite particles involves providing a carbon scaffold comprising a pore volume, where the pore volume comprises ≥ 70% microporosity, heating the porous carbon scaffold to a temperature from 300-500℃, contacting the carbon scaffold with a silane feedstock gas, where the XSi of the process is greater than 50%, where the XSi is 100×(mole of silicon in the silicon-carbon composite)/(mole silane feedstock gas), the mole silicon in the silicon-carbon composite is determined from the silicon content in the silicon-carbon composite by thermogravimetric analysis.