• 专利标题:   Forming graphene-like material or graphene used in nanofluids comprises forming polycyclic aromatic hydrocarbon (PAH) liquid solution, forming layer of PAH solution on surface of layer of water and evaporating solvent from layer of solution.
  • 专利号:   US2013284338-A1, KR2013121030-A, DE102013207010-A1, CN103373727-A, KR2015035949-A, CN103373727-B
  • 发明人:   XIAO X, LIU Z
  • 专利权人:   GM GLOBAL TECHNOLOGY OPERATIONS INC, GM GLOBAL TECHNOLOGY OPERATIONS INC, GM GLOBAL TECHNOLOGY OPERATIONS INC, GM GLOBAL TECHNOLOGIES OPERATIONS INC
  • 国际专利分类:   B32B037/14, B82Y040/00, C01B031/04, C07C005/00, C01B031/02, C01B031/36
  • 专利详细信息:   US2013284338-A1 31 Oct 2013 B32B-037/14 201377 Pages: 9 English
  • 申请详细信息:   US2013284338-A1 US456263 26 Apr 2012
  • 优先权号:   US456263

▎ 摘  要

NOVELTY - Method (m1) of forming graphene-like material (20) or graphene comprises: forming a liquid solution of a polycyclic aromatic hydrocarbon (PAH) in a solvent so that the solution will float on the surface of a layer of water (16) without substantial dissolution or extraction of the PAH into the water; forming a layer of the solution of the PAH on the surface of a layer of water; and evaporating the solvent from the layer of solution of the PAH. USE - The method is useful for forming graphene-like material or graphene (claimed) which is useful in nanofluids. ADVANTAGE - The method: is cost-effective; produces easily storable or transferable graphene layers; produces the graphene-like material which provides improved thermal conductivity for nanofluids; and utilizes inexpensive water as the supporting liquid layer for the initial solution of the PAH material. DETAILED DESCRIPTION - Method (m1) of forming graphene-like material (20) or graphene comprises: forming a liquid solution of a polycyclic aromatic hydrocarbon (PAH) in a solvent so that the solution will float on the surface of a layer of water (16) without substantial dissolution or extraction of the PAH into the water; forming a layer of the solution of the PAH on the surface of a layer of water; and evaporating the solvent from the layer of solution of the PAH to form a residual layer of PAH, graphene-like material on the layer of water. The layer of water and the overlying layer of the solution are contained to form a surface area for a desired planar configuration for the solution of PAH. The residual layer of polycyclic hydrocarbon is in the form of a substantially molecular film of organized molecules of PAH that are substantially compliant with the surface of the water layer. The film has a thickness of less than a nanometer. INDEPENDENT CLAIMS are also included for: (1) a method (m2) of forming graphene-like material or graphene comprising: (a) forming a liquid solution of the PAH in an aromatic organic compound solvent so that the solution is immiscible with water; (b) forming a layer of the water-immiscible solution of the PAH on the surface of a layer of water of a depth up to a few millimeters at an ambient temperature and without heating, the layer of water is contained on a base (15) of solid material and confined on its sides to form a surface area for a desired planar configuration of the graphene or graphene-like material; (c) reducing the atmospheric pressure over the solution layer and evaporating the solvent from the layer of solution of the PAH to form a residual layer of PAH on the layer of water, where the residual layer of polycyclic hydrocarbon is in the form of a film of a continuous body or discontinuous bodies of organized molecules of PAH that are substantially compliant with the surface of the water layer, and the film has a thickness of less than a few nanometers; (d) evaporating the water layer to deposit the film of organized molecules of PAH onto the base of solid material; and (e) heating the film of organized molecules of PAH in a vacuum or inert atmosphere to reduce the content of hydrogen atoms in the material to leave a carbon-enriched residue on the solid material, where the carbon-enriched residue is characterized by at least one two-dimensional layer of connected six-member rings of carbon atoms, in nature of graphene; and (2) a method (m3) of forming graphene-like material or graphene comprising: forming a liquid solution of a PAH in a first solvent; forming a layer of the solution of PAH on an underlying supporting layer of a liquid that is immiscible with the liquid solution; evaporating the first solvent to form a substantially single molecular layer of the PAH on the liquid supporting layer; and removing the liquid supporting layer and depositing the molecular layer of PAH on a substrate as a graphene-like material. DESCRIPTION OF DRAWING(S) - The figure shows an enlarged view of the processing system or arrangement using a rectangular shaped processing pan with four vertical sides and a flat base. Pan (12) Solid plate member (14) Base (15) Layer of water (16) Graphene-like material (20)