• 专利标题:   Making graphene oxide-coated graphitic foil, used in e.g. heat dissipation system, comprises e.g. forming graphene oxide gel having graphene oxide molecules, and depositing gel on surface of core or substrate layer of graphitic material.
  • 专利号:   US2018144843-A1
  • 发明人:   ZHAMU A, XIONG W, JANG B Z
  • 专利权人:   NANOTEK INSTR INC
  • 国际专利分类:   H01B001/04, C01B032/192, C01B032/198, B82Y040/00, B82Y030/00
  • 专利详细信息:   US2018144843-A1 24 May 2018 H01B-001/04 201837 Pages: 25 English
  • 申请详细信息:   US2018144843-A1 US862199 04 Jan 2018
  • 优先权号:   US694161, US862199

▎ 摘  要

NOVELTY - Producing a graphene oxide-coated graphitic foil, comprises: (a) preparing a core or substrate layer of a graphitic material; (b) preparing a graphene oxide gel having graphene oxide molecules dispersed in a fluid medium, where graphene oxide gel is optically transparent or translucent; (c) depositing graphene oxide gel onto a surface of the core or substrate layer to form a coating on it; (d) partially or completely removing the fluid medium from the coating to form a coated laminate; and (e) heat-treating the coated substrate or coated laminate to form graphene oxide-coated graphitic foil. USE - The process is useful for producing a graphene oxide-coated graphitic foil (claimed), which is useful in heat dissipation system or thermal management system. ADVANTAGE - The process provides the graphene-coated graphitic foil, which: has a thermal conductivity of greater than or equal to 600 W/mK, preferably 600-1900 W/mK, a physical density of greater than or equal to 1.4 g/cm3, preferably 1.4-2.24 g/cm3, electrical conductivity of 5000-20000 S/cm, and a tensile strength of greater than or equal to 10 MPa, preferably greater than 40-20 MPa and a Rockwell hardness of 60-88 (claimed), hence exhibits improved thermal conductivity, electrical conductivity, mechanical strength, surface scratch resistance and hardness; and exhibits less or no tendency to flake off. DETAILED DESCRIPTION - Producing a graphene oxide-coated graphitic foil, comprises: (a) preparing a core or substrate layer of a graphitic material; (b) preparing a graphene oxide gel having graphene oxide molecules dispersed in a fluid medium, where the graphene oxide gel is optically transparent or translucent; (c) depositing graphene oxide gel onto a surface of the core or substrate layer to form a coating on it; (d) partially or completely removing the fluid medium from the coating to form a coated laminate; and (e) heat-treating the coated substrate or the coated laminate to form the graphene oxide-coated graphitic foil. The graphene oxide coating layer has a thickness of 1 nm to 10 mm, and an oxygen content of 0.01-40 wt.% based on the total graphene oxide weight, and comprises a unitary graphene layer or a single crystal of oriented graphene planes that are parallel to one another. The graphene-coated graphitic foil has a thickness of 10 mu m to 10 mm, a thermal conductivity of greater than or equal to 600 W/mK, a physical density of greater than or equal to 1.4 g/cm3, and a tensile strength of greater than or equal to 10 MPa.