▎ 摘　　要

NOVELTY - An electrochemically active self-assembled film composite material is prepared by forming amphiphilic molecule complexes on the ITO substrate surface by bond, where amphiphilic molecules are immobilized ruthenium complexes on surface, assembling pyrenyl graphene role in amphiphilic ruthenium complex molecules by two layers of graphene film and ruthenium complexes interconnected, after repeated alternately immersed in solution of zirconium oxychloride and symmetry ruthenium complex solution, and connecting between symmetry and ruthenium complex molecule to give number of layers of membrane. USE - Electrochemically active self-assembled film composite material. ADVANTAGE - The material has good mechanical and chemical stability, electrochemical performance, stability, high strength with substrate and good application value, and can be operated without special conditions and complex and expensive equipment, and shape of the base material not affected, in simple, easy and cost effective manner. DETAILED DESCRIPTION - An electrochemically active self-assembled film composite material is prepared by forming amphiphilic molecule complexes on the ITO substrate surface by a covalent bond, where the amphiphilic molecules are immobilized ruthenium complexes on the ITO surface, assembling pyrenyl graphene role in the amphiphilic ruthenium complex molecules by two layers of graphene film and ruthenium complexes interconnected, after repeated alternately immersed in a solution of zirconium oxychloride and symmetry ruthenium complex solution, the zirconium ion by amphiphilic molecules and ruthenium complexes Ruthenium complexes molecular symmetry, and connecting between symmetry and the ruthenium complex molecule to give number of layers and thickness of the composite membrane, where the amphiphilic ruthenium complex has structure of formula (I) and (Ru (XPOH)2) (PF6)2 ruthenium symmetry complex of formula (II). An INDEPENDENT CLAIM is also included for a method for preparing electrochemically active self-assembled film composite material, which involves adding ultrapure water in a clean container with ammonia to pH 10-12, dissolving amphiphilic complexes in ultrapure water, to obtain 10-100 mu M amphiphilic nail complex solution, taking clean container weighed oxygen dissolved in ultrapure lead chloride aqueous solution, to obtain 10-30 mM lead chloride solution, adding ultrapure water in a clean container with ammonia to pH 10-12 modulation weighed symmetry nail complexes dissolved in ultrapure water, adjusted to 5-6 to obtain 10-100 mu M symmetry nail complex solution followed by dissolving sulfuric acid in water to give 2% SDS solution, dispersing graphite in SDS aqueous solution at 2: 10-4: 10, separating from the residue after removal of the bottom of the ultrasonic dispersion treatment, to obtain 0.1-0.3 mg/ml graphite dispersing liquid, preparing solution of RCA in a beaker, immersing ITO substrate in RCA solution, with gentle shaking water bath, removing the pot bubbles moved, after heating ITO substrate with ultrapure water washing and drying under inert gas to obtain product.