• 专利标题:   Preparation of 2,3-dichloropyridine by chlorination includes reacting 3-aminopyridine, hydrochloric acid and hydrogen peroxide in graphene oxide.
  • 专利号:   CN113582918-A, CN113582918-B
  • 发明人:   SONG L, ZHANG X, WANG W, ZHANG S, WANG B
  • 专利权人:   INNER MONGOLIA YUANHONG FINE CHEM CO LTD
  • 国际专利分类:   C07D213/61, C07D213/73
  • 专利详细信息:   CN113582918-A 02 Nov 2021 C07D-213/61 202225 Chinese
  • 申请详细信息:   CN113582918-A CN10806179 16 Jul 2021
  • 优先权号:   CN10806179

▎ 摘  要

NOVELTY - Preparation of 2,3-dichloropyridine by chlorination comprises reacting 3-aminopyridine, 20-35 wt.% hydrochloric acid and 20-30 wt.% hydrogen peroxide in the presence of graphene oxide to obtain 2-chloro-3-aminopyridine and converting 2-chloro-3-aminopyridine into 2,3-dichloropyridine. USE - The method is used for preparation of 2,3-dichloropyridine by chlorination. ADVANTAGE - The method reduces formation of 2,6-dichloro-3-aminopyridine and concentration and dosage of hydrochloric acid and hydrogen peroxide, improves selectivity of 2-position chlorination and has high quality, high yield and good environmental protection and economy,