• 专利标题:   Composite material used in preparation of negative electrode, comprises specified amount of tin dioxide, graphene, and nickel ferrite.
  • 专利号:   CN107046127-A
  • 发明人:   HAO Q, YAN S, LEI W, XIA X
  • 专利权人:   UNIV NANJING SCI TECHNOLOGY
  • 国际专利分类:   H01M010/0525, H01M004/36, H01M004/48, H01M004/525, H01M004/583, H01M004/62
  • 专利详细信息:   CN107046127-A 15 Aug 2017 H01M-004/36 201770 Pages: 9 Chinese
  • 申请详细信息:   CN107046127-A CN10160766 17 Mar 2017
  • 优先权号:   CN10160766

▎ 摘  要

NOVELTY - A composite material comprises tin dioxide, nickel ferrite and graphene. The content of tin dioxide is 10-70 wt.% with respect to content of composite material. The content of graphene is 25-30 wt.% with respect to content of composite material. USE - Composite material is used in preparation of negative electrode (claimed). ADVANTAGE - The composite material has excellent stability. By adjusting content rate of tin dioxide, the lithium storage performance of the composite material is improved. The negative electrode obtained using the composite material has current density of 0.2 A.g-1, specific capacity of 500-700 mAh.g-1 after 50 cycles, and initial discharge capacity of 50-80%. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) preparation of composite material, which involves mixing ferric nitrate heptahydrate and nickel nitrate hexahydrate in deionized water, adding ethylene glycol solution of stannous chloride, stirring, adding aqueous graphite oxide solution, mixing uniformly, adding urea to the resultant mixed solution, stirring, performing hydrothermal reaction, cooling the resultant mixture, centrifuging, washing, and drying; and (2) usage method of composite material in preparation of negative electrode, which involves mixing the composite material, electroconductive carbon black and polyvinylidene fluoride in mass ratio of 8:1:1, coating the resultant mixture on a copper foil, drying and obtaining negative electrode.