• 专利标题:   Anion decorative paper comprises base film layer arranged on outer side of anion layer and the anion layer, moisture-proof and antibacterial layer is made of wet weaving, and heating layer is provided with graphene patch.
  • 专利号:   CN113718557-A
  • 发明人:   QIAO Y
  • 专利权人:   QIAO Y
  • 国际专利分类:   D21H017/07, D21H017/14, D21H017/67, D21H019/10, D21H019/38, D21H019/40, D21H019/44, D21H019/46, D21H019/56, D21H021/24, D21H021/36, D21H027/20, E04F013/00
  • 专利详细信息:   CN113718557-A 30 Nov 2021 D21H-027/20 202232 Chinese
  • 申请详细信息:   CN113718557-A CN10961377 20 Aug 2021
  • 优先权号:   CN10961377

▎ 摘  要

NOVELTY - Anion decorative paper comprises a decorative paper layer. The decorative paper layer includes a base film layer, an anion layer, a heating layer, and a moisture-proof and antibacterial layer, and the anion layer, the heating layer and the moisture-proof and antibacterial layer are sequentially arranged from top to bottom. The base film layer is arranged on the outer side of the anion layer and the anion layer, the moisture-proof and antibacterial layer is made of wet weaving, and the heating layer is provided with a graphene patch. USE - Used as anion decorative paper. ADVANTAGE - The paper is environmentally friendly, removes harmful substances e.g. formaldehyde and indoor odors, antibacterial and antibacterial, and anti-mildew and antibacterial, prevents the veneer products from being damaged by moisture, and saves indoor heat for a long time. DETAILED DESCRIPTION - Anion decorative paper comprises a decorative paper layer. The decorative paper layer includes a base film layer, an anion layer, a heating layer, and a moisture-proof and antibacterial layer, and the anion layer, the heating layer and the moisture-proof and antibacterial layer are sequentially arranged from top to bottom. The base film layer is arranged on the outer side of the anion layer and the anion layer, the moisture-proof and antibacterial layer is made of wet weaving, and the heating layer is provided with a graphene patch. The components of the anion layer: 5-30 pts. wt. anion additive, 15-30 pts. wt. pigment filler, 20-40 pts. wt. de-ionized water, 35-65 pts. wt. macromolecule tourmaline, 15-20 pts. wt. surfactant, 20-30 pts. wt. tourmaline-resin compound, 20-40 pts. wt. aqueous acrylic acid emulsion, 40-60 pts. wt. superfine heavy calcium carbonate, 0.5-5 pts. wt. zeolite, 3-15 pts. wt. mineral filler, 0.01-0.2 pts. wt. dispersant, 0.5-2 pts. wt. film-forming auxiliary agent, and 9-12 pts. wt. allyl benzene propylene. The moisture-proof antibacterial solution comprises 75-85 wt.% de-ionized water, 2-4 wt.% ammonium hexafluorozirconate, 3-7 wt.% sodium dodecylbenzene sulfonate, 5.5-7.5 wt.% stabilizing agent, 0.1-0.5 wt.% benzisothiazolinone, 0.1-2.25 wt.% N-octyl isothiazolinone, 0.25-0.75 wt.% pH value regulator and 0.1-0.25 wt.% sodium carbonate. An INDEPENDENT CLAIM is also included for processing anion decorative paper, comprising (i) placing the magnetic powder, rare earth, sodium carbonate, potassium silicate in the above-mentioned negative ion additives and the manganese dioxide, titanium dioxide, strontium earth and talc powder in the mineral fillers into the ultrafine powder mixer, and the mixing speed is 600-1000 revolutions/minute to obtain the micropowder mixture, (ii) adding the micro powder mixture, zeolite and polymer tourmaline particles to the stirring tank and stir evenly, the stirring speed is 800-1300 revolutions/minute, after stirring, injecting deionized water and pigments and fillers for heating, the heating temperature is 220-300degreesC, one standard atmosphere, and the heating time is 1-1.5 hours, the initial solvent of the coating, (iii) adding the initial coating solvent and water-based acrylic emulsion, fine heavy calcium carbonate and tourmaline-resin compound to a high-speed disperser for stirring, and the stirring time is 15-30 minutes to obtain the anion layer mixture, (iv) adding the negative ion layer mixture, styrene and propylene and dispersant to the reaction kettle for stirring, the stirring speed is 800-1000 revolutions/minute, the stirring time is 24-34 minutes, and the heating is performed after the stirring is completed, the heating temperature is 220-325degreesC, one standard atmospheric pressure, heating time 0.5-1 hours, adding surfactant and film-forming assistant and stir at low speed, the stirring speed is 200-350 revolutions/minute, after the stirring is finished, cooling to room temperature naturally to obtain the anion layer base material, (v) mixing deionized water, ammonium hexafluorozirconate, sodium dodecylbenzene sulfonate, stabilizer, benzisothiazoline, N-octylisothiazolinone, adding pH value regulator and sodium carbonate to the stirring tank and uniformly, the stirring speed is 800-1600 revolutions/minute, after stirring, heating is carried out, the heating temperature is 70-90degreesC, and the heating is stopped when the viscosity reaches between 4-6 Pa.s, after heating, cooling naturally to room temperature to obtain moisture-proof and antibacterial composite liquid, (vi) placing the moisture-proof and antibacterial composite liquid into a wet-laid weaving machine, and process the moisture-proof and antibacterial textile layer by wet-laid spinning, drying the moisture-proof and antibacterial layer woven by the wet method, and drying at 70-85degreesC for 15-30 minutes, and (vii) placing the base film layer of the processed decorative paper into liquid nitrogen for quick freezing, apply the moisture-proof and antibacterial composite liquid, and paste the moisture-proof and antibacterial layer on top, and placing the graphene patch on the moisture-proof and antibacterial layer, applying the negative ion layer base material evenly on the upper surface of the quick-frozen graphene patch, the thickness of the negative ion layer base material on the decorative paper layer is 1-2.2 mm, after the application is completed, the base film layer is pasted on the top and dried, and the initial drying temperature is 25degreesC, rising uniformly at a rate of 10degreesC/minutes until it rises to 70-85degreesC, and continue to drying for 20-25 minutes.