• 专利标题:   Preparing high temperature oxidation resistant carbon fiber toughened zirconia ceramic material used as heat insulation layer of rockets, involves depositing zirconium oxide layer on surface of graphene oxide modified carbon fibers coated with alumina to form modified carbon fibers.
  • 专利号:   CN113845367-A, CN113845367-B
  • 发明人:   WU D, HOU Z, WU B
  • 专利权人:   JIANGXI XINDAHANGKE NEW MATERIAL TECHNOL
  • 国际专利分类:   C04B035/48, C04B035/622, C04B035/64, C04B035/80
  • 专利详细信息:   CN113845367-A 28 Dec 2021 C04B-035/80 202215 Chinese
  • 申请详细信息:   CN113845367-A CN11171649 08 Oct 2021
  • 优先权号:   CN11171649

▎ 摘  要

NOVELTY - The preparation of the high-temperature oxidation-resistant carbon fiber toughened zirconia ceramic material involves: taking graphene oxide modified carbon fibers coated with alumina as a base material, zirconium chloride as a zirconium source precursor, carbon dioxide and hydrogen as reaction gas, and argon used as diluent gas; depositing a zirconium oxide layer on the surface of the base material using a chemical vapor deposition method to form modified carbon fibers; mixing zirconium oxide powder with the particle size of 45-75 microm, zirconium tungstate powder, modified carbon fiber and sintering aid; adding the mixture into a ball mill, and adding phenolic resin, graphite powder and deionized water for ball milling; vacuum treating the slurry, dry pressing molding, and curing for 6-12 hours at 50-90 degrees Celsius; and heating at 1400-1500 degrees Celsius in a vacuum furnace and an inert atmosphere at a rate of 5-10 degrees Celsius/minute, carrying out heat preservation sintering for 2-6 hours, and cooling. USE - Preparation method of high temperature oxidation resistant carbon fiber toughened zirconia ceramic material used as heat insulation layer of rockets, a cylinder sleeve and a piston top of an internal combustion engine, various nozzles, ceramic valves, continuous casting nozzles and crucibles in smelting. ADVANTAGE - The method enables to prepare carbon fiber toughened zirconia ceramic material with high temperature oxidation resistance and improved toughness. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for the high temperature oxidation resistant carbon fibre toughened zirconia ceramic material.