• 专利标题:   Epitaxial graphene growth and transfer on gallium nitride substrate by chemical vapor deposition and chemical etching involves placing silicon carbide substrate in metal organic chemical vapor deposition reactor and adding ammonia.
  • 专利号:   CN103606514-A, CN103606514-B
  • 发明人:   HAO Y, NING J, WANG D, ZHANG J, CHAI Z, HAN D, YAN Y
  • 专利权人:   UNIV XIDIAN
  • 国际专利分类:   C30B025/02, C30B025/18, C30B029/02, H01L021/205
  • 专利详细信息:   CN103606514-A 26 Feb 2014 H01L-021/205 201432 Chinese
  • 申请详细信息:   CN103606514-A CN10647163 03 Dec 2013
  • 优先权号:   CN10647163

▎ 摘  要

NOVELTY - Epitaxial graphene growth and transfer on gallium nitride substrate by chemical vapor deposition and chemical etching involves placing surface of silicon carbide substrate (6H-SiC) in metal organic chemical vapor deposition (MOCVD) reactor, adding gallium and ammonia mixed gas, reacting for 0.5-1 hour, producing 1-3 mu m gallium nitride substrate, growing graphene by chemical vapor deposition for 10-20 minutes, cooling to room temperature, spin coating polymethyl methacrylate, air drying, soaking in 0.5 g/mL potassium hydroxide solution and removing gallium nitride layer by chemical etching. USE - Epitaxial graphene growth and transfer on gallium nitride substrate by chemical vapor deposition and chemical etching (claimed). DETAILED DESCRIPTION - Epitaxial graphene growth and transfer on gallium nitride substrate by chemical vapor deposition and chemical etching comprises placing surface of silicon carbide substrate (6H-SiC) in metal organic chemical vapor deposition (MOCVD) reactor, adding gallium and ammonia mixed gas with gallium flow of 50-200 mu mol/minute and ammonia flow of 1000-3000 standard cm3/minute, reacting for 0.5-1 hour, producing 1-3 mu m gallium nitride substrate, vacuumizing, ensuring pressure is not higher than 10-6 torr, depositing 1-2 mu m copper film by electron beam evaporation on gallium nitride substrate, adding hydrogen gas with flow rate of 1-20 standard cm3/minute, heating at 900-1000 degrees C, thermal annealing copper film for 20-60 minutes, adding hydrogen gas with flow rate of 20-200 standard cm3/minute and methane with flow rate of 2-20 standard cm3/minute, growing graphene by chemical vapor deposition for 10-20 minutes, cooling to room temperature, removing, spin coating polymethyl methacrylate, air drying, soaking in 0.5 g/mL potassium hydroxide solution, removing gallium nitride layer by chemical etching, peeling silicon carbide substrate layer, removing copper film from potassium hydroxide solution, floating on 50-70 g/L ammonium dithionite (NH4)3(S2O4)2 aqueous solution, removing copper film by chemical etching, removing from ammonium dithionite solution, heating at 120 degrees C for 30 minutes, adding insulating substrate, cooling, soaking in acetone, removing polymethyl methacrylate, washing with ethanol and drying with pure nitrogen.