• 专利标题:   Heterogeneous photocatalyst used during degradation of organic pollutant, comprises graphene and bismuth molybdate, and has good degradation effect on rhodamine B in visible light.
  • 专利号:   CN103623809-A, CN103623809-B
  • 发明人:   HUANG Q, LUO S, XING Q, MA J, ZOU J
  • 专利权人:   UNIV NANCHANG HANGKONG
  • 国际专利分类:   B01J023/31, B01J037/10, C02F001/30, C02F101/38
  • 专利详细信息:   CN103623809-A 12 Mar 2014 B01J-023/31 201431 Pages: 8 Chinese
  • 申请详细信息:   CN103623809-A CN10377686 27 Aug 2013
  • 优先权号:   CN10377686

▎ 摘  要

NOVELTY - Heterogeneous photocatalyst comprises graphene and bismuth molybdate that has two different formula Bi2MoO6 and Bi3.64Mo0.35O6.55, where graphite is 1% of the total mass of bismuth molybdate. The catalyst has good degradation effect on rhodamine B in visible light. USE - Heterogeneous photocatalyst used during degradation of organic pollutant. ADVANTAGE - The heterogeneous photocatalyst is pure, stable, acid resistance and alkali resistance, and ensures simple preparation in high yield and cost-effective manner. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing heterogeneous photocatalyst, which involves: (A) obtaining graphite oxide using improved Hummers oxidation method; (B) dispersing graphite oxide in deionized water using ultrasonic wave for 2 hours to obtain graphene oxide dispersion liquid; (C) dispersing bismuth nitrate in deionized water; (D) adding ammonium key(sic) to nitrate solution; (E) stirring to obtain solution A; (F) diluting graphene oxide dispersion with water to obtain solution B; (G) stirring solution B with solution A at normal temperature for 30 minutes; (H) adding hydrazine hydrate, absolute ethyl alcohol and ammonia water in polytetrafluoroethylene reaction kettle for hydro-thermal synthesis at pH 8.5; (I) keeping reaction mixture in muffle furnace at 150 degrees C for 5 hours to finish reaction; and (J) filtering and vacuum drying at 60 degrees C for 24 hours to obtain catalyst.