• 专利标题:   Preparation of lithium iron phosphate composite positive electrode material involves reacting ferrous sulfate, phosphoric acid and lithium hydroxide, adding excessive reducing agent, and adding reduced graphene oxide/lithium iron phosphate.
  • 专利号:   CN114784249-A, CN114784249-B
  • 发明人:   ZHOU L, WANG W, XUE L, WANG H, YI C
  • 专利权人:   CHUNENG NEW ENERGY CO LTD
  • 国际专利分类:   H01M004/36, H01M004/58, H01M004/587
  • 专利详细信息:   CN114784249-A 22 Jul 2022 H01M-004/36 202275 Chinese
  • 申请详细信息:   CN114784249-A CN10464935 29 Apr 2022
  • 优先权号:   CN10464935

▎ 摘  要

NOVELTY - Preparation of lithium iron phosphate composite positive electrode material involves (S1) mixing ferrous sulfate, phosphoric acid and lithium hydroxide, heating for reaction, cooling the reaction product, filtering, cleaning, and vacuum drying to obtain lithium iron phosphate, and grinding, (S2) soaking the ground lithium iron phosphate in a graphene oxide solution, adding an excessive reducing agent, heating and reducing to obtain reduced graphene oxide/lithium iron phosphate, filtering and drying, and (S3) adding sodium anthraquinone-2,6-disulfonate and pyrrole into deionized water, dissolving to obtain a solution (A), adding ferric trichloride into deionized water, dissolving to obtain a solution (B), adding reduced graphene oxide/lithium iron phosphate into the solution (A), shaking and dripping the solution (B) at 0℃, reacting completely, filtering and drying. USE - Preparation of lithium iron phosphate composite positive electrode material (claimed). ADVANTAGE - The method provides lithium iron phosphate composite positive electrode material having excellent electrical conductivity and lithium ion diffusion property.