• 专利标题:   Preparing nano silver/pyridine functionalized graphene modified electrode comprises adding silver nitrate and ethylenediaminetetraacetic acid into pyridine-graphene oxide, heating, adding sodium borohydride, centrifuging and drying.
  • 专利号:   CN111707720-A
  • 发明人:   HE J, DU L, YANG J, YAO Y
  • 专利权人:   UNIV CHONGQING ARTS SCI
  • 国际专利分类:   B22F001/00, B22F009/24, B82Y030/00, C01B032/194, G01N027/30, G01N027/48
  • 专利详细信息:   CN111707720-A 25 Sep 2020 G01N-027/30 202081 Pages: 14 Chinese
  • 申请详细信息:   CN111707720-A CN10668384 13 Jul 2020
  • 优先权号:   CN10668384

▎ 摘  要

NOVELTY - Preparing nano silver/pyridine functionalized graphene modified electrode comprises synthesizing pyridine functionalized graphene, silver nanoparticles/pyridine functionalized graphene and silver nanoparticles/pyridine functionalized graphene/glassy carbon electrode preparation, adding silver nitrate and ethylenediaminetetraacetic acid into the pyridine-graphene oxide dispersion to form mixed solution, heating in a water bath, then slowly adding sodium borohydride, heating, centrifuging and drying. USE - The electrode is useful in detecting hydroquinone and pyrocatechol (claimed). ADVANTAGE - The electrode: has high loading of silver i.e. 39.62 wt.%, uniform size of silver nanoparticles, uniformly distributed on the surface of graphene; has no agglomeration; excellent detection sensitivity for HQ and CC, and has the detection limits of 0.062 mu M and 0.097 mu M respectively; and excellent selectivity and strong anti-interference ability. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for electrode useful in detecting hydroquinone and pyrocatechol.