• 专利标题:   Synthesizing furoic acid by electrochemical conversion of furfural cathode useful for food preservative, comprises rolling electrode catalytic layer and current collector, calcining, cooling, electrolyzing, adding furfural into electrolyte solution and carrying out constant pressure electrolysis.
  • 专利号:   CN114438525-A
  • 发明人:   LIN N, CONG L, LI X, LIN H
  • 专利权人:   UNIV JILIN
  • 国际专利分类:   C25B003/05, C25B003/07, C25B003/23
  • 专利详细信息:   CN114438525-A 06 May 2022 C25B-003/07 202292 Chinese
  • 申请详细信息:   CN114438525-A CN10078150 24 Jan 2022
  • 优先权号:   CN10078150

▎ 摘  要

NOVELTY - Synthesizing furoic acid by electrochemical conversion of furfural cathode comprises e.g. (i) mixing the carbon material and the binder at ratio of (1-7):(3-1), dispersing ultrasonically in ethanol solution, stirring and heating to paste at 60-90℃, rolling to form a sheet and vacuum drying at 45-60℃ for 12-24 hours to obtain the electrode catalytic layer; (ii) combining above-mentioned electrode catalytic layer and the current collector treated with the binder by rolling, calcining in an inert gas atmosphere for 0.1-2 hours at 250-370℃ and cooling naturally to obtain the gas diffusion electrode; (iii) carrying out electrolysis using a diaphragm-type electrochemical reactor, and the diaphragm is a cation exchange membrane; and (iv) taking the electrolyte is 0.01-1 mol/liter electrolyte solution, and adding 0.01-1 mol/liter furfural into the catholyte. USE - The method is useful for synthesizing furoic acid by electrochemical conversion of furfural cathode is useful for food preservative, plastic plasticizer and medicine. ADVANTAGE - The method: uses green and environmentally-friendly oxygen; avoids the use of noble metal homogeneous catalyst and subsequent separation step; realizes the green synthesis process; does not use toxic and harmful reagent; easily available raw material; is simple to operate and economical; and produces economical and environmentally-friendly furoic acid with improved purity and yield.