• 专利标题:   Manufacture of polyvinyl carbazole/graphene composite material used for photoelectric information material, involves treating functionalized graphite oxide and polyvinyl carbazole with ultrasonic wave, reducing, filtering and drying.
  • 专利号:   CN101845189-A, CN101845189-B
  • 发明人:   LI L, WEI Y, MU H, SHANG J
  • 专利权人:   WUHAN INST TECHNOLOGY
  • 国际专利分类:   C08K003/04, C08K009/04, C08L039/04
  • 专利详细信息:   CN101845189-A 29 Sep 2010 C08L-039/04 201109 Pages: 5 Chinese
  • 申请详细信息:   CN101845189-A CN10177900 14 May 2010
  • 优先权号:   CN10177900

▎ 摘  要

NOVELTY - Graphite oxide obtained by treating natural graphite, and phenyl isocyanate are reacted in N,N-dimethylformamide at 60-90 degrees C for 12-48 hours, extracted, filtered, washed and dried to obtain functionalized graphite oxide. The obtained oxide and polyvinyl carbazole are treated with ultrasonic wave for 0.5-2 hours in organic solvent, reducing agent is added, reacted at 60-100 degrees C for 24-48 hours, product is added into methanol, precipitated, filtered and vacuum-dried to obtain polyvinyl carbazole/graphene composite material. USE - Manufacture of polyvinyl carbazole/graphene composite material used for photoelectric information material. ADVANTAGE - The polyvinyl carbazole/graphene composite material is economically manufactured with improved carrier transmission characteristics. DETAILED DESCRIPTION - Graphite oxide having one or more layers is obtained by treating natural graphite by chemical oxidation method. The graphite oxide and phenyl isocyanate are reacted in N,N-dimethylformamide at 60-90 degrees C for 12-48 hours, extracted, filtered, washed and dried to obtain functionalized graphite oxide. The ratio of graphite oxide with respect to phenyl isocyanate is 50 mg:1-5 mmol. The obtained oxide and polyvinyl carbazole are treated with ultrasonic wave for 0.5-2 hours in organic solvent, reducing agent is added, reacted at 60-100 degrees C for 24-48 hours, product is added into methanol, precipitated, filtered and vacuum-dried, to obtain polyvinyl carbazole/graphene composite material. The ratio of functionalized graphite oxide with respect to polyvinyl carbazole (mg) is 50:2-10. The ratio of polyvinyl carbazole with respect to reducing agent (mg) is 50:2-6.