• 专利标题:   Preparation of nitrogen-doped graphene nanobelt-nano-cobalt tetroxide hybrid material by subjecting original carbon nanotube to chemical radial shearing, obtaining graphene oxide nano-aqueous dispersion, and adding cobalt salt.
  • 专利号:   CN107746051-A
  • 发明人:   LIU T, LU H, FAN W, GAO W, ZUO L
  • 专利权人:   UNIV FUDAN
  • 国际专利分类:   B01J023/75, B82Y030/00, B82Y040/00, C01B032/184, C01G051/04
  • 专利详细信息:   CN107746051-A 02 Mar 2018 C01B-032/184 201824 Pages: 10 Chinese
  • 申请详细信息:   CN107746051-A CN11014289 26 Oct 2017
  • 优先权号:   CN11014289

▎ 摘  要

NOVELTY - Preparation of nitrogen-doped graphene nanobelt-nano-cobalt tetroxide hybrid material comprises subjecting the original carbon nanotube to chemical radial shearing, obtaining graphene oxide nano-aqueous dispersion, taking graphene oxide nano-aqueous dispersion, adding cobalt salt, ultrasonically treating, adding ammonia water, continuously stirring to obtain uniform mixed solution, transferring to hydrothermal kettle, conducting one-step hydrothermal reaction, taking the black precipitates, washing with deionized water, and oven drying to obtain the product. USE - Preparation of nitrogen-doped graphene nanobelt-nano-cobalt tetroxide hybrid material (claimed) used as oxygen reduction reaction catalyst material. ADVANTAGE - The method provides graphene oxide nanobelt with large aspect ratio, and cobalt tetroxide nanoparticles, which are smaller in size and uniformly distributed on graphene nanobelt. DETAILED DESCRIPTION - Preparation of nitrogen-doped graphene nanobelt-nano-cobalt tetroxide hybrid material comprises subjecting the original carbon nanotube to chemical radial shearing, obtaining graphene oxide nano-aqueous dispersion, taking 15-25 ml graphene oxide nano-aqueous dispersion, adding 0.1-0.4 mmol cobalt salt, ultrasonically treating for 30-60 minutes, adding 2-4 ml ammonia water, continuously stirring for 10-15 minutes to obtain uniform mixed solution, transferring to hydrothermal kettle, conducting one-step hydrothermal reaction at 150-180 degrees C for 3-4 hours, taking the black precipitates, washing with deionized water for 3-5 times, and oven drying to obtain the product, where nano-cobalt tetroxide particles having particle size of 5-10 nm are uniformly distributed on nitrogen-doped graphene nanobelt. An INDEPENDENT CLAIM is included for nitrogen-doped graphene nanobelt-nano-cobalt tetroxide hybrid material.