• 专利标题:   Powder mass of multiple porous graphene balls gas storage for underground supply systems, comprises multiple graphene sheets having catalyst, in form of nanoparticles or coating, bonded to or supported by graphene sheet surfaces.
  • 专利号:   US2020317524-A1
  • 发明人:   ZHAMU A, CHAI S, JANG B Z
  • 专利权人:   NANOTEK INSTR INC
  • 国际专利分类:   C01B032/192, C01B032/198, C01B032/225
  • 专利详细信息:   US2020317524-A1 08 Oct 2020 C01B-032/192 202085 Pages: 12 English
  • 申请详细信息:   US2020317524-A1 US374176 03 Apr 2019
  • 优先权号:   US374176

▎ 摘  要

NOVELTY - Powder mass of multiple porous graphene balls, comprises multiple graphene sheets having a catalyst, in a form of nanoparticles or coating having a diameter or thickness from 0.3-10 nm, bonded to or supported by graphene sheet surfaces, where porous graphene balls having a diameter from 0.1-100 mu m, a physical density from 0.01-1.7 g/cm3, and a specific surface area from 50-3,000 m2/g and where the catalyst is in an amount from 0.01-50% by weight of the total graphene ball weight. USE - The graphene ball is useful in gas storage for underground supply systems. ADVANTAGE - The graphene ball: significantly increases the capacity of gas species storage of the graphene-based materials; is an economical and simple approach, is safe and portable; and solves the problem of explosion hazard. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for (1) a gas storage device containing the powder mass as a gas-absorbing, gas-adsorbing, gas-capturing, or gas-storing medium to store a gas species in it; and (2) a method of producing the powder mass, comprising either (a) providing a suspension of multiple graphene sheets dispersed in a liquid medium where a catalyst or a catalyst precursor is dispersed or dissolved in the liquid medium or where the catalyst is pre-deposited on surfaces of the graphene sheets in a form of nanoparticles or coating, and (b) dispensing the suspension into multiple micro-droplets and thermally or chemically converting the micro-droplets into the mass of porous graphene balls or (A) providing a suspension of multiple graphene sheets dispersed in a liquid medium, (B) dispensing the suspension into multiple micro-drop- lets and removing the liquid from the micro-droplets to form porous micro-droplets comprising multiple graphene sheets and pores, and (C) impregnating the pores with a catalyst or a catalyst precursor and thermally or chemically converting the catalyst precursor to the catalyst to obtain the multiple porous graphene balls. DESCRIPTION OF DRAWING(S) - The drawing shows a flowchart illustrating the method for two processes that can be used to produce the porous graphene balls for gas storage. Porous graphene ball structure (1)