• 专利标题:   Catalyst used in preparation of toluene and xylene by alkylation of benzene and methanol, comprises graphene oxide-containing molecular sieves and metal oxides, where morphology of catalyst is multi-stage porous column.
  • 专利号:   CN115990509-A
  • 发明人:   ZOU W, REN S
  • 专利权人:   CHINA PETROLEUM CHEM CORP SINOPEC, CHINA PETROLEUM CHEM CORP
  • 国际专利分类:   B01J029/40, B01J035/10, C07C015/06, C07C015/08, C07C002/86
  • 专利详细信息:   CN115990509-A 21 Apr 2023 B01J-029/40 202345 Chinese
  • 申请详细信息:   CN115990509-A CN11218667 19 Oct 2021
  • 优先权号:   CN11218667

▎ 摘  要

NOVELTY - Catalyst comprises graphene oxide-containing molecular sieves and metal oxides. The morphology of the catalyst is a multi-stage porous column. USE - The catalyst is used in preparation of toluene and xylene by alkylation of benzene and methanol (claimed). ADVANTAGE - When the catalyst is used in the alkylation reaction of benzene and methanol, it can efficiently improve the conversion rate of benzene, the selectivity of toluene and xylene, and reduces the selectivity of by-product ethylbenzene. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing the catalyst, comprising (1) mixing silicon source, aluminum source, organic template and water to prepare a mixed solution, (2) mixing the graphene oxide dispersion with the mixed solution prepared in step (1), and crystallizing to obtain a molecular sieve containing graphene oxide, and (3) loading the metal source on the graphene oxide-containing molecular sieve to prepare the catalyst.