• 专利标题:   Preparation of expanded polystyrene-modified graphene molded product used in e.g. electrical applications, involves intercalation of graphite, peeling graphene layer, washing using alcohol, modifying and polymerizing using e.g. styrene.
  • 专利号:   CN108084306-A
  • 发明人:   HOU S, SHEN H
  • 专利权人:   JILIN YUNTING GRAPHENE TECHNOLOGY CO LTD
  • 国际专利分类:   C01B032/19, C01B032/194, C08F112/08, C08F002/44, C08J009/14, C08J009/20, C08K003/04, C08K007/00, C08K007/24, C08K009/00, C08K009/02, C08K009/04
  • 专利详细信息:   CN108084306-A 29 May 2018 C08F-112/08 201843 Pages: 9 Chinese
  • 申请详细信息:   CN108084306-A CN11225261 29 Nov 2017
  • 优先权号:   CN11225261

▎ 摘  要

NOVELTY - Preparation of expanded polystyrene-modified graphene molded product involves mixing graphite and oxide intercalation agent comprising acid, nitrate and potassium permanganate, carrying out continuous expansion of intercalated graphite for 20-200 seconds using 915 MHz high-frequency microwave, controlling the output power to 100-200 KW, carrying out ultrasonic peeling to form 3-5 graphene layer, discharging, mixing graphene with alcohol in a mass ratio of 1:5-10 for 1-5 hours, washing using alcohol, modifying, drying, and carrying out suspension polymerization using 30-35 %mass styrene, 0.25-0.65 %mass graphene, 0.05-0.2 %mass initiator, 0.4-1 %mass dispersant, 0.05-0.1 %mass additive, 2.5-4 %mass foaming agent pentane and 59.05-66.75 %mass pure water. The graphite has a purity of more than 99% and a particle size of 50-200 mesh. The mass ratio of graphite, acid, nitrate and potassium permanganate is 1:1-5:0.1-0.5:0.1-0.5. USE - Preparation of expanded polystyrene-modified graphene molded product used in military industry and electrical applications. ADVANTAGE - The prepared molded product has excellent dispersibility, conductivity, mechanical properties, surface resistance of up to 106-1012 ( Omega ), tensile strength of 0.7-1.0 MPa, compressive strength of 0.35-0.45 MPa, and flame retardant rating of B1 level.