• 专利标题:   Manufacture of cobalt/graphene composite material involves dispersing graphite oxide in glycol solution, adding cobalt salt, anhydrous sodium acetate and polyethylene glycol, heating, cooling, centrifuging, washing and drying.
  • 专利号:   CN102229425-A, CN102229425-B
  • 发明人:   LI Y, WANG H, ZHANG F, ZHANG Q
  • 专利权人:   UNIV DONGHUA
  • 国际专利分类:   B82Y030/00, C01B031/04
  • 专利详细信息:   CN102229425-A 02 Nov 2011 C01B-031/04 201221 Pages: 7 Chinese
  • 申请详细信息:   CN102229425-A CN10077569 29 Mar 2011
  • 优先权号:   CN10077569

▎ 摘  要

NOVELTY - Graphite oxide is dispersed in glycol solution at room temperature to obtain mixed solution having density of 0.5-2 mg/mL. The mixed solution is ultrasonically dispersed for 30-60 minutes. Cobalt salt, anhydrous sodium acetate and polyethylene glycol are added to the mixed solution, and mixed for 1-2 hours to obtain reaction liquid. The reaction liquid is added into reaction container, heated at 180-210 degrees C for 8-16 hours, cooled at room temperature, centrifuged, washed with deionized water and absolute ethyl alcohol, and dried to obtain cobalt/graphene composite material. USE - Manufacture of cobalt/graphene composite material by alcohol heat method. ADVANTAGE - The method provides pure cobalt/graphene composite material having high dispersibility, magnetizability, and compounding ability of cobalt crystal with graphene, and reduced electrical resistivity, by simple process. DETAILED DESCRIPTION - Graphite oxide is dispersed in glycol solution at room temperature to obtain mixed solution having density of 0.5-2 mg/mL. The mixed solution is ultrasonically dispersed for 30-60 minutes. Cobalt salt, anhydrous sodium acetate and polyethylene glycol are added to the mixed solution, and mixed for 1-2 hours to obtain reaction liquid. The reaction liquid is added into reaction container, heated at 180-210 degrees C for 8-16 hours, cooled at room temperature, centrifuged, washed with deionized water and absolute ethyl alcohol, and dried to obtain cobalt/graphene composite material. The mass ratio of cobalt salt and graphite oxide is 1:1-5:1. The mass ratio of anhydrous sodium acetate and cobalt salt is 10-1:12-1. The volume ratio of polyethylene glycol and glycol is 1-110:1-550.