• 专利标题:   Preparing silicon-based cathode self-repairing polymer adhesive used in preparation of silicon negative electrode sheets of lithium ion batteries, involves adding polyethylene glycol diacrylate to lipoic acid, stirring, mixing, reacting.
  • 专利号:   CN113054193-A, CN113054193-B
  • 发明人:   ZHU D, WU L, LIN Z, LAN M, JIANG K, CHEN Z, WANG S, LI X
  • 专利权人:   UNIV GUANGDONG TECHNOLOGY
  • 国际专利分类:   H01M010/0525, H01M004/04, H01M004/134, H01M004/62
  • 专利详细信息:   CN113054193-A 29 Jun 2021 H01M-004/62 202170 Pages: 10 Chinese
  • 申请详细信息:   CN113054193-A CN10271607 12 Mar 2021
  • 优先权号:   CN10271607

▎ 摘  要

NOVELTY - Preparing silicon-based cathode self-repairing polymer adhesive involves adding polyethylene glycol diacrylate to lipoic acid, where ratio of zinc sulfate to polyethylene glycol diacrylate is 1 g:25-200 mu L, stirring and reacting at 50-100 degrees C for 1 to 5 hours to obtain polylipoic acid cross-linked by polyethylene glycol; mixing polyethylene glycol cross-linked polylipoic acid and polyacrylic acid, and dissolved in water or organic solvent at mass ratio of 1:1-20, reacting and drying to obtain polymer adhesive. USE - Method for preparing silicon-based cathode self-repairing polymer adhesive used in preparation of silicon negative electrode sheets of lithium ion batteries (claimed). ADVANTAGE - The method enables to prepare polymer binder, which has strong self-repairing ability, high elongation at break, improves stable specific capacity in cycle process of lithium ion battery silicon-based cathode, and prolongs service life of lithium ion battery. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing silicon negative electrode sheet for lithium ion battery, which involves: (A) weighing silicon-based cathode self-repairing polymer adhesive, silicon-based active material, and conductive agent in proportion; (B) dispersing in solvent for mixing; and (C) coating slurry on surface of copper foil, and drying to obtain electrode sheet.