• 专利标题:   Preparing cellulose-based conductive complex film by fermenting Acetobacter xylinum in fermentation medium, washing, freezing and curing biocellulose liquid film, drying, soaking in reduced graphene oxide/silver nanowire mixture, freezing and curing, drying and performing hot-pressing treatment.
  • 专利号:   CN113501996-A, CN113501996-B
  • 发明人:   GAO W, LI J, XU J, CHEN K, WANG B, ZENG J, CHENG Z
  • 专利权人:   UNIV SOUTH CHINA TECHNOLOGY
  • 国际专利分类:   C12R001/02, C12P019/04, C08K007/06, C08K003/04, C08L001/02, C08J009/40
  • 专利详细信息:   CN113501996-A 15 Oct 2021 C08J-009/40 202102 Chinese
  • 申请详细信息:   CN113501996-A CN10625223 04 Jun 2021
  • 优先权号:   CN10625223

▎ 摘  要

NOVELTY - Method for preparing cellulose-based conductive complex film involves (a) inoculating Acetobacter xylinum into fermentation medium, performing static fermentation at 30-34degreesC and relative humidity of 56-60%, and then using dilute alkali solution and deionized water to wash the static fermentation product to neutrality and obtain a biocellulose liquid film, (b) freezing and curing the biocellulose liquid film obtained in step (a) and then vacuum drying to obtain a biocellulose aerogel, (c) dissolving graphene and silver nanowires (AgNWs) in water in a mass ratio of 1:1-3 and ultrasonically mixing in an ice water bath to obtain reduced graphene oxide (rGO)/AgNWs mixed solution, (d) soaking the biocellulose aerogel obtained in step (b) in rGO/AgNWs mixture obtained in step (c), then freezing and curing and vacuum drying to obtain conductive biocellulose aerogel and (e) subjecting the conductive biocellulose aerogel obtained in step (d) to hot-pressing treatment. USE - The method is useful for preparing cellulose-based conductive complex film which is used in conductive material (claimed). ADVANTAGE - The method prepares complex film which has good flexibility, high mechanical properties and good electrical conductivity and can be completely degraded.