• 专利标题:   Preparation of manganese-doped zinc sulfide quantum-dot surface imprinting fluorescent probe for detection of acrylamide in food, involves mixing manganese-doped zinc sulfide graphene oxide with e.g. methacrylate, eluting and drying.
  • 专利号:   CN105237677-A, CN105237677-B
  • 发明人:   QIU J, LIU Y, NI L, MENG X
  • 专利权人:   UNIV JIANGSU
  • 国际专利分类:   B01J020/26, B01J020/30, C08F002/44, C08F220/06, C08F220/56, C08F222/14, C08K003/08, C08K003/30, C08K009/06, C09K011/02, C09K011/54, C09K011/57, G01N021/64
  • 专利详细信息:   CN105237677-A 13 Jan 2016 C08F-220/56 201643 Pages: 12 English
  • 申请详细信息:   CN105237677-A CN10701834 27 Oct 2015
  • 优先权号:   CN10701834

▎ 摘  要

NOVELTY - Preparation of manganese-doped zinc sulfide quantum-dot surface imprinting fluorescent probe involves preparing silane-modified manganese-doped zinc sulfide quantum dot, dissolving graphene oxide in ethanol, adding KH-580 (RTM: long-chain alkyl silane), heating, washing, drying, obtaining manganese-doped zinc sulfide graphene oxide, adding resultant product and dimethylformamide to three-necked flask, adding propionamide pseudo template, methacrylate, ethylene glycol dimethacrylate and azobisisobutyronitrile, sealing, washing, filtering, drying, eluting and drying. USE - Preparation of manganese-doped zinc sulfide quantum-dot surface imprinting fluorescent probe used for detection of acrylamide in food (claimed). ADVANTAGE - The method enables preparation of manganese-doped zinc sulfide quantum-dot surface imprinting fluorescent probe having excellent luminescence efficiency and sensitivity and high detection rate, within short period of time. DETAILED DESCRIPTION - Preparation of manganese-doped zinc sulfide quantum-dot surface imprinting fluorescent probe involves adding zinc sulfate heptahydrate, manganese chloride tetrahydrate and deionized water to three-necked flask, dissolving, mixing at room temperature in nitrogen atmosphere, dripping aqueous solution of sodium sulfide nonahydrate, stirring continuously, centrifuging, obtaining manganese-doped zinc sulfide quantum dot, washing, drying, dispersing resultant in ethanol solution, stirring, dripping KH-580 (RTM: long-chain alkyl silane), refluxing, washing, drying, leaving still, obtaining silane-modified manganese-doped zinc sulfide quantum dot, dissolving graphene oxide in ethanol, stirring, adding KH-580 (RTM: long-chain alkyl silane), heating, washing, vacuum-drying, obtaining manganese-doped zinc sulfide graphene oxide, adding resultant product and dimethylformamide to three-necked flask, ultrasonically dispersing, adding propionamide pseudo template, methacrylate, ethylene glycol dimethacrylate and azobisisobutyronitrile, sealing, washing, filtering, vacuum-drying, adding to mixture comprising methanol and acetic acid in Soxhlet extractor, eluting and vacuum-drying.