• 专利标题:   Composite material-loaded metal oxide catalyst used in degradation of sewage, comprises copper oxide/ceria as active component, and epoxy resin-chitosan-graphene oxide as carrier.
  • 专利号:   CN107570212-A
  • 发明人:   WU M, MENG X, WANG J, SHAO Y, CHEN L, SUN Y, NI H, MA Q, ZHENG Y
  • 专利权人:   UNIV SOUTHEAST
  • 国际专利分类:   B01J020/26, B01J020/30, B01J031/28, C02F001/28, C02F001/66, C02F001/72, C02F101/38
  • 专利详细信息:   CN107570212-A 12 Jan 2018 B01J-031/28 201814 Pages: 12 Chinese
  • 申请详细信息:   CN107570212-A CN10933288 10 Oct 2017
  • 优先权号:   CN10933288

▎ 摘  要

NOVELTY - A composite material-loaded metal oxide catalyst is represented by copper oxide/ceria-epoxy resin-chitosan-graphene oxide, and comprises copper oxide/ceria as an active component, and epoxy resin-chitosan-graphene oxide as a carrier. The ratio of active component copper oxide/ceria and chitosan is 0.5-5:0.5-5:100. USE - Composite material-loaded metal oxide catalyst used in degradation of sewage (claimed). ADVANTAGE - The composite material-loaded metal oxide catalyst has high activity, catalytic stability, and mechanical strength, and excellent catalytic effect, large specific surface area, and adsorption property, and is suitable for degrading sewage with chemical oxygen demand concentration of 3000-30000 mg/l. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) preparation of metal oxide catalyst, which involves dispersing epoxy resin, chitosan, and graphene oxide in phosphoric acid solution, adding surfactant, cerium nitrate hexahydrate, and copper nitrate trihydrate, where the ratio of cerium nitrate hexahydrate, copper nitrate trihydrate, and chitosan is 0.5-5:0.5-5:100, stirring, adding ethanol solution, reacting, adding glutaraldehyde, crosslinking, washing the precipitate, and dry-grinding; and (2) degradation of sewage with metal oxide catalyst, which involves adding copper oxide/ceria-epoxy resin-chitosan-graphene oxide catalyst into a sewage solution with a chemical oxygen demand concentration of 3000-30000 mg/l, heating at 60-70 degrees C, dripping hydrogen peroxide solution at a rate of 2.4-3.6 ml/minute, adjusting the pH to 7-8, and reacting for 30-40 minutes.