• 专利标题:   Magnetic nanoparticles useful in adsorbing triazine herbicides including ametrazine, terbuthylazine, another butylazine, atrazine and trietazine, comprise nucleosome (made of graphene oxide modified superparamagnetic ferric oxide), shell covering at least part of surface of core body.
  • 专利号:   CN115869899-A
  • 发明人:   WANG X, XU X, XIE Y, ZHANG F
  • 专利权人:   CHINA ACAD INSPECTION QUARANTINE
  • 国际专利分类:   B01D015/00, B01J020/02
  • 专利详细信息:   CN115869899-A 31 Mar 2023 B01J-020/02 202337 Chinese
  • 申请详细信息:   CN115869899-A CN11687093 27 Dec 2022
  • 优先权号:   CN11687093

▎ 摘  要

NOVELTY - Magnetic nanoparticles comprise nucleosome, the nucleosome is made of graphene oxide modified superparamagnetic ferric oxide; shell, the shell covers at least part of the surface of the core body, and the shell is composed of (2Z,4E,6E)-2,4-bis(aminomethylene)-6-(((4-(4,6-bis(4-aminophenyl)-1,3,5-triazin-2-yl)phenyl)amino)methylene)cyclohexane-1,3,5-trione based repeating unit (I). USE - The magnetic nanoparticles are useful in adsorbing triazine herbicides including ametrazine, terbuthylazine, another butylazine, atrazine and trietazine (all claimed). ADVANTAGE - The graphene oxide-modified magnetic nanoparticles: contains core body, which is made of graphene oxide-modified super-paramagnetic ferric oxide; contains shell, and composed of repeating units (I); has super-paramagnetism, and have the advantages of large specific surface area and porous structure; can adsorb and enrich triazine herbicides existing in complex samples, and has strong adsorption capacity and fast speed. DETAILED DESCRIPTION - Magnetic nanoparticles comprise nucleosome, the nucleosome is made of graphene oxide modified superparamagnetic ferric oxide; shell, the shell covers at least part of the surface of the core body, and the shell is composed of (2Z,4E,6E)-2,4-bis(aminomethylene)-6-(((4-(4,6-bis(4-aminophenyl)-1,3,5-triazin-2-yl)phenyl)amino)methylene)cyclohexane-1,3,5-trione based repeating unit of formula (I). INDEPENDENT CLAIMS are also included for: Preparing magnetic nanoparticles, comprising contacting graphene oxide-modified superparamagnetic iron ferric oxide nanoparticles with tris(4-aminophenyl)amine and ultrasonicating, and then performing first stirring, thus to obtain the first mixture; and contacting the first mixture with trialdehyde phloroglucinol and a catalyst and performing a second stirring, thus to obtain final product; Adsorbing triazine herbicides using the magnetic nanoparticles.