• 专利标题:   Preparation of graphene-hard carbon composite used for manufacturing electrochemical capacitor, involves adding graphite oxide to water, ultrasonically dispersing, adding formaldehyde and phenol, polymerizing, heating, and cooling.
  • 专利号:   CN104064366-A
  • 发明人:   LIU D, WANG Y, ZHONG H, ZHOU M
  • 专利权人:   OCEANS KING LIGHTING SCI TECHNOLOGY CO, SHENZHEN OCEANS KING LIGHTING ENG CO LTD, SHENZHEN OCEANS KING LIGHTING SCI TECH
  • 国际专利分类:   H01G011/38, H01G011/84, H01G011/86
  • 专利详细信息:   CN104064366-A 24 Sep 2014 H01G-011/38 201501 Pages: 12 Chinese
  • 申请详细信息:   CN104064366-A CN10086514 18 Mar 2013
  • 优先权号:   CN10086514

▎ 摘  要

NOVELTY - Graphite oxide is added to water, and ultrasonically dispersed, to obtain graphene oxide suspension. The pH of graphene oxide suspension is adjusted to 2-5, formaldehyde, phenol and polyoxyethylene-polyoxypropylene-polyoxyethylene-type triblock copolymer are added, heated under stirring, and polymerization reaction is carried out. Obtained reactant is placed under inert protective gas atmosphere, heated at 800-900 degrees C for 0.5-2 hours, and cooled, to obtain graphene-hard carbon composite. The mass ratio of graphene oxide and phenol is 5:0.05-3. USE - Preparation of graphene-hard carbon composite for manufacturing electrochemical capacitor (all claimed). ADVANTAGE - The graphene-hard carbon composite having high specific surface area is manufactured. DETAILED DESCRIPTION - Graphite oxide is added to water, and ultrasonically dispersed, to obtain graphene oxide suspension. The pH of graphene oxide suspension is adjusted to 2-5, formaldehyde, phenol and polyoxyethylene-polyoxypropylene-polyoxyethylene-type triblock copolymer are added, heated under stirring, and polymerization reaction is carried out. Obtained reactant is placed under inert protective gas atmosphere, heated at 800-900 degrees C for 0.5-2 hours, and cooled, to obtain graphene-hard carbon composite. The mass ratio of graphene oxide and phenol is 5:0.05-3. The mass ratio of formaldehyde, phenol and polyoxyethylene-polyoxypropylene-polyoxyethylene-type triblock copolymer is 54-65:50:1-10. INDEPENDENT CLAIMS are included for the following: (1) electrochemical capacitor; and (2) manufacture of electrochemical capacitor.