• 专利标题:   Thermosonic sintering of nano silver and graphene composite ink comprises e.g. taking anhydrous ethanol, polyethylene glycol and glycerol mixing together by ultrasonic vibration, forming mixed organic solvent and stirring nano silver powder.
  • 专利号:   CN106211606-A, CN106211606-B
  • 发明人:   WANG F, ZHU H, HE H, LI J, ZHU W
  • 专利权人:   UNIV CENT SOUTH, UNIV CENT SOUTH
  • 国际专利分类:   C09D011/52, H05K001/09, H05K003/12
  • 专利详细信息:   CN106211606-A 07 Dec 2016 H05K-003/12 201711 Pages: 11 Chinese
  • 申请详细信息:   CN106211606-A CN10576017 20 Jul 2016
  • 优先权号:   CN10576017

▎ 摘  要

NOVELTY - Thermosonic sintering of nano silver/graphene composite ink comprises e.g. taking anhydrous ethanol, polyethylene glycol and glycerol mixing together by ultrasonic vibration, forming a mixed organic solvent having a viscosity of 0.01-100 Pas; and stirring 96-99.9 wt.% nano silver powder and the graphene by the mechanical stirring method, 4-0.1 wt.% graphene dispersing in mixed organic solvents, and configuring 0.01-90 wt.% nano silver/graphene composite ink, then, mixing nano silver/graphene compound ink uniformly filling in the dispensing head to prepare the circuit writing. USE - The method is useful for thermosonic sintering of nano silver/graphene composite ink (claimed). ADVANTAGE - The method has good electrical conductivity and mechanical bending performance (claimed). DETAILED DESCRIPTION - Thermosonic sintering of nano silver/graphene composite ink comprises (i) taking anhydrous ethanol, polyethylene glycol and glycerol mixing together by ultrasonic vibration, forming a mixed organic solvent having a viscosity of 0.01-100 Pas; and stirring 96-99.9 wt.% nano silver powder and the graphene by the mechanical stirring method, 4-0.1 wt.% graphene dispersing in mixed organic solvents, and configuring 0.01-90 wt.% nano silver/graphene composite ink, then, mixing nano silver/graphene compound ink uniformly filling in the dispensing head to prepare the circuit writing; (ii) extruding the high viscosity nano silver/graphene composite ink from the plastic cylinder by air pressure, and the forming a flexible substrate with a conductive circuit on a flexible substrate by a dispensing head; finally, drying the printed circuit board with a flexible conductive substrate in oven at 55-65 degrees C for 2-4 hours, to remove the volatile organic solvent; then, taking out the flexible substrate having the conductive circuit, for the next step of sintering; (iii) drying dried flexible substrate with the conductive circuit, placing between two layers of polydimethylsiloxane protective plastic, the polydimethylsiloxane has a thickness of 100-500 mu m, and placing the flexible substrate on the heating table; pressing the end of the ultrasonic transducer on a flexible substrate, applying a pressure to the flexible substrate to a desired value of 3-30 MPa; heating the substrate to a heating temperature of 60-160 degrees C; and then, under conditions of 3-30 MPa and 60-160 degrees C; hot-pressing pre-sintering, the sintering time is 1-10 minutes, and then, 3-30 MPa, 60-160 degrees C under the conditions, turning on ultrasonic vibration, carrying out thermosonic sintering, the sintering time is 1-10 minutes, through the role of ultrasound, pressure and temperature, to achieve solid-state diffusion between nano-silver/graphene. An INDEPENDENT CLAIM is also included for device comprising nano silver/graphene composite ink writing system and nano silver/graphene composite ink thermosonic sintering system, the writing system of the nano silver/graphene compound ink has the following structure: the writing base is provided with a writing column and upper and lower translation table and a writing motion translation stage, the writing column and the upper and lower translation table is provided with a writing fixing holder, the writing fixing holder is provided with a writing force sensor and the plastic tube, the upper end of the rubber cylinder is connected with a gas pipe and an air pressure controller, the lower end of the plastic tube connected to a little plastic head; the writing motion translation stage, a writing column and a vertical translation stage, writing force sensors and air pressure controller and writing the control computer using a communication connection; the thermosonic sintering system of the nano silver/graphene composite ink has the following structure: the sintering base is provided with a sintering column and a vertical translation table and a sintering movement translation stage, the sintering column and the vertical translation table is provided with a sintering fixing holder, the sintering fixing holder is provided with a sintering force sensor and a transducer, the transducer is connected with an ultrasonic generator, the transducer provided with a horn tip, the front end of the horn is provided with the tool head; the sintering movement translation table is provided with a heating platform; the sintering column and the vertical translation table, sintering motion translation stage, the heating table sintering force sensor and ultrasonic generator and the sintering control computer is communicatively connected.