• 专利标题:   Preparing graphene quantum dot based on heterogeneous catalyst, comprises e.g. dispersing manganese dioxide particles in water, adding hydrogen peroxide and neutral graphene oxide solution into reaction solution, then adding hydrochloric acid and hydrogen peroxide, and post-processing.
  • 专利号:   CN115924896-A
  • 发明人:   WANG J, LU Y, GE M, ZHANG F, CUI D
  • 专利权人:   SHANGHAI NAT ENG RES CENT NANOTECHNOLOGY
  • 国际专利分类:   B01J023/34, C01B032/184, C01B032/19, C09K011/65
  • 专利详细信息:   CN115924896-A 07 Apr 2023 C01B-032/184 202341 Chinese
  • 申请详细信息:   CN115924896-A CN11674694 26 Dec 2022
  • 优先权号:   CN11674694

▎ 摘  要

NOVELTY - Preparing graphene quantum dot based on heterogeneous catalyst, comprises (i) dispersing manganese dioxide particles in water and stirring vigorously, (ii) maintaining stirring, boiling the dispersion obtained in step (i), stopping heating and adding hydrogen peroxide, (iii) immediately adding neutral graphene oxide solution into reaction solution obtained in step (ii), continuously stirring, maintaining boiling slightly, and adding hydrogen peroxide properly, (iv) stopping heating, continuously stirring, adding hydrochloric acid and hydrogen peroxide to convert all manganese dioxide into manganese(II) ions, and (v) filtering the reaction solution obtained in step (iv), and dialyzing the obtained liquid to obtain final product. USE - The method is useful for preparing graphene quantum dot based on heterogeneous catalyst. ADVANTAGE - The method has simple device, easy to process the product, does not require ultraviolet light irradiation, and does not introduce impurities.