• 专利标题:   Method for manufacturing graphene transparent conductive film, involves preparing graphene oxide-alkene, surface modifying, dispersing, discharging, drying, extruding, stretching, and preparing composite electric conductive coating.
  • 专利号:   CN105788753-A, CN105788753-B
  • 发明人:   LIU C, LIU G, LIU Y
  • 专利权人:   SHENZHEN VKIRIN TECHNOLOGICAL DEV CO LTD, SHENZHEN VKIRIN TECHNOLOGICAL DEV CO LTD
  • 国际专利分类:   H01B001/02, H01B001/04, H01B001/08, H01B001/24, H01B013/00
  • 专利详细信息:   CN105788753-A 20 Jul 2016 H01B-013/00 201673 Pages: 12 Chinese
  • 申请详细信息:   CN105788753-A CN10822977 24 Dec 2014
  • 优先权号:   CN10822977

▎ 摘  要

NOVELTY - A graphene transparent conductive film manufacturing method involves preparing graphene oxide-alkene, followed by surface modifying graphene oxide-alkene, ultrasonically dispersing in organic solvent, vacuum condensation heating, discharging, drying, extruding, stretching, preparing a composite electric conductive coating, adding dispersing agent mixed liquid, adding polymer resin, ultrasonically and continuously mixing, performing centrifugal separation, and coating graphene modified polyethylene terephthalate film to obtain a graphene transparent conductive film. USE - Method for manufacturing a graphene transparent conductive film. ADVANTAGE - The method enables preparing the transparent conductive film with high electric resistance and light transmittance. DETAILED DESCRIPTION - A graphene transparent conductive film preparing method involves preparing graphene oxide-alkene, followed by surface modifying graphene oxide-alkene in organic solvent using silane coupling agent. The surface modified graphene oxide-alkene is ultrasonically dispersed in organic solvent, mixing terephthalic acid, ethylene glycol, catalyst and stabilizer, vacuum condensation heating and discharging to obtain modified polyester polyethylene terephthalate film. The modified polyester polyethylene terephthalate film is dried, extruded and stretched by two-way stretching to obtain graphene modified polyethylene terephthalate film, followed by preparing a composite electric conductive coating by ultrasonically mixing nano-metal aqueous solution, graphene-oxide and antimony tin oxide/indium tin oxide solution with weight ratio of 1-10:1-10:1-10 to obtain mixed liquid, adding 0.1-5 pts. wt. dispersing agent to 100 pts. wt. mixed liquid, adding 1-10 pts. wt. polymer resin having uniform molecule weight (Mn) of less than 10000, ultrasonically and continuously mixing for 10-60 minutes and performing centrifugal separation to obtain the supernatant as composite electric conductive coating. The composite electric conductive coating is coated with graphene modified polyethylene terephthalate film to obtain graphene transparent conductive film. An INDEPENDENT CLAIM is also included for a graphene transparent conductive film prepared by the method.