• 专利标题:   Preparation of anti-dripping antistatic high-tenacity flame-retardant polyester used for water-proof fabric, involves mixing polyethylene terephthalate with mixture of flame retardant, phenolic antioxidant and modified graphene oxide.
  • 专利号:   CN105177753-A, CN105177753-B
  • 发明人:   DENG Y, GENG X, LU S, TANG J, YANG Y, YU M, YU Y, ZHANG X, ZHANG Y, ZHOU R
  • 专利权人:   UNIV DONGHUA, JIANGSU JINZE NEW MATERIAL CO LTD, JIANGSU JINZE NEW MATERIAL CO LTD
  • 国际专利分类:   D01D013/00, D01D005/14, D01F001/07, D01F001/09, D01F006/92
  • 专利详细信息:   CN105177753-A 23 Dec 2015 D01F-006/92 201642 Pages: 7 English
  • 申请详细信息:   CN105177753-A CN10688803 21 Oct 2015
  • 优先权号:   CN10688803

▎ 摘  要

NOVELTY - Preparation of anti-dripping antistatic high-tenacity flame-retardant polyester involves dissolving graphene oxide in deionized water, ultrasonically processing, dripping p-phenylenediamine, reacting, obtaining modified graphene oxide, mixing polyethylene terephthalate with mixture of flame retardant, anti-dripping masterbatch, phenolic antioxidant and modified graphene oxide, heating, pressing, stretching resultant fiber through hot-oil, then stretching the nascent fiber through boiling water, washing, drying and winding. USE - Preparation of anti-dripping antistatic high-tenacity flame-retardant polyester used for water-proof fabric for military clothing and military tent (all claimed). ADVANTAGE - The method enables economical preparation of anti-dripping antistatic high-tenacity flame-retardant polyester with high productivity. DETAILED DESCRIPTION - Preparation of anti-dripping antistatic high-tenacity flame-retardant polyester involves dissolving graphene oxide in deionized water, ultrasonically processing, obtaining stable dispersion liquid, heating to 80-95 degrees C, dripping p-phenylenediamine, reacting for 2-4 hours, filtering, cleaning, drying, obtaining modified graphene oxide, mixing polyethylene terephthalate with mixture of flame retardant, anti-dripping masterbatch, phenolic antioxidant and modified graphene oxide, adding resultant product into a twin-screw extruder, heating, obtaining molten spinning solution, pressing the spinning solution into a spinning component, circularly blowing in the constant temperature and humidity environment, cooling, obtaining nascent fiber, stretching the nascent fiber through hot-oil, then stretching the nascent fiber through boiling water, relaxing at high temperature for thermoforming, washing, drying and winding. The ratio of p-phenylenediamine and graphene oxide is 20-25:1.