• 专利标题:   Method for preparing graphene/zinc oxide core-shell structured composite material for cathode of super capacitor, involves dispersing graphene into N,N-dimethyl formamide, followed by assembly negative electrode with positive electrode.
  • 专利号:   CN106158416-A, CN106158416-B
  • 发明人:   WANG Y, YAN X, CHEN Z, ZHANG J, LI H
  • 专利权人:   UNIV CHINA ELECTRONIC SCI TECHNOLOGY, SICHUAN ENERGY TECHNOLOGY CO LTD
  • 国际专利分类:   H01G011/30, H01G011/36, H01G011/46, H01G011/84
  • 专利详细信息:   CN106158416-A 23 Nov 2016 H01G-011/84 201681 Pages: 10 Chinese
  • 申请详细信息:   CN106158416-A CN10693194 22 Aug 2016
  • 优先权号:   CN10693194

▎ 摘  要

NOVELTY - A graphene/zinc oxide core-shell structured composite material preparing method involves dispersing graphene into N,N-dimethyl formamide. Zinc nitrate solution and acetylacetone is mixed, dropped ammonia water into mixed solution. The solution is stirred and the solution is centrifuged or filtered, washed and dried. The zinc acetylacetonate powder is added into graphene dispersion liquid. The negative electrode is soaked into electrolytic solution by electrode activation process. The negative electrode is assembled with the positive electrode to form super capacitor. USE - Method for preparing graphene/zinc oxide core-shell structured composite material for cathode of super capacitor. ADVANTAGE - The method enables preparing the graphene/zinc oxide core-shell structured composite material with high specific capacity and better cycling stability. DETAILED DESCRIPTION - A graphene/zinc oxide core-shell structured composite material preparing method involves dispersing graphene into N,N-dimethyl formamide to obtain graphene dispersion. Zinc nitrate solution and acetylacetone is mixed, dropped ammonia water into mixed solution to adjust pH value of the solution 1-7. The solution is stirred and the solution is centrifuged or filtered, washed and dried to obtain zinc acetylacetonate powder. The zinc acetylacetonate powder is added into graphene dispersion liquid, the surface of the graphene is stirred to cover the zinc acetylacetonate, followed by transferring the solution system in zinc acetylacetonate into reaction kettle, reacting reaction kettle under hydro-thermal reaction at 50-250 degrees C for 1-48 hours, centrifuging or filtering the product, washing and drying to obtain graphene/zinc oxide core-shell structure composite material. The graphene/zinc oxide core-shell structure composite material as a cathode material, conductive agent and binding agent are mixed uniformly and coated mixed solution on the surface of collector after drying to obtain negative electrode. The negative electrode is soaked into electrolytic solution by electrode activation process. The negative electrode is assembled with the positive electrode to form super capacitor.