• 专利标题:   Molecularly imprinted electrochemical sensor for detecting patulin, comprises glassy carbon electrode, thioindigo-platinum nanoparticle-nitrogen-doped graphene composite nanomaterial layer and molecularly imprinted polymer layer.
  • 专利号:   CN108693229-A
  • 发明人:   HAN Z, NIE D, ZHAO Z, JIANG K, HUANG Q, GUO W, MENG J
  • 专利权人:   SHANGHAI AGRIC SCI ACAD
  • 国际专利分类:   G01N027/30, G01N027/48
  • 专利详细信息:   CN108693229-A 23 Oct 2018 G01N-027/30 201883 Pages: 10 Chinese
  • 申请详细信息:   CN108693229-A CN10495371 22 May 2018
  • 优先权号:   CN10495371

▎ 摘  要

NOVELTY - A molecularly imprinted electrochemical sensor comprises a glassy carbon electrode, a thioindigo-platinum nanoparticle-nitrogen-doped graphene composite nanomaterial layer and molecularly imprinted polymer layer, where the a thioindigo-platinum nanoparticle-nitrogen-doped graphene composite nanomaterial layer is coated on surface of the glassy carbon electrode and the molecularly imprinted polymer layer is coated on surface a thioindigo-platinum nanoparticle-nitrogen-doped graphene composite nanomaterial layer. USE - Molecularly imprinted electrochemical sensor for detecting patulin. ADVANTAGE - The molecularly imprinted electrochemical sensor has improved detection efficiency, can be prepared in simple, accuracy, rapid and cost effective manner. DETAILED DESCRIPTION - A molecularly imprinted electrochemical sensor for detecting patulin comprises a glassy carbon electrode, a thioindigo-platinum nanoparticle-nitrogen-doped graphene composite nanomaterial layer and molecularly imprinted polymer layer, where the a thioindigo-platinum nanoparticle-nitrogen-doped graphene composite nanomaterial layer is coated on surface of the glassy carbon electrode and the molecularly imprinted polymer layer is coated on surface a thioindigo-platinum nanoparticle-nitrogen-doped graphene composite nanomaterial layer, a thioindigo-platinum nanoparticle-nitrogen-doped graphene composite nanomaterial layer is prepared by preparing a mixture aqueous solution platinum chloride and aqueous hydrochloric acid, dispersing nitrogen-doped graphene in mixed solution, centrifuging, collecting black reaction product is collected, washing with acetonitrile, water and drying to obtain a platinum nanoparticle-nitrogen-doped graphene composite nanomaterial, mixing thiopurine, adding dimethylformamide and centrifuging to obtain the finished product and the molecularly imprinted polymer layer is a molecularly imprinted polymer layer formed by electropolymerization using thioindole as a polymerization monomer and patulin as a template molecule.