• 专利标题:   Graphene-iron iron oxide-polyaniline ternary nano composite material with adjustable wave absorption properties comprises reduced graphene oxide, polyaniline, and rest is ferric oxide.
  • 专利号:   CN111154258-A
  • 发明人:   JIN Y, LUO X, ZHANG J, YU Y, WU B, LU F, QI Y
  • 专利权人:   CENT IRON STEEL RES INST
  • 国际专利分类:   C08G073/02, C08K003/04, C08K003/22, C08L079/02, C09K003/00, H05K009/00
  • 专利详细信息:   CN111154258-A 15 May 2020 C08L-079/02 202048 Pages: 13 Chinese
  • 申请详细信息:   CN111154258-A CN11377245 27 Dec 2019
  • 优先权号:   CN11377245

▎ 摘  要

NOVELTY - Graphene-iron iron oxide-polyaniline ternary nanocomposite material with adjustable wave absorption properties comprises 10-30 wt.% reduced graphene oxide, 10-60 wt.% polyaniline, and the rest is ferric oxide. The composite material is obtained by reducing graphene oxide-ferroferric oxide binary nanoparticles and aniline through low-temperature polymerization by changing the content ratio of reduced graphene oxide-ferroferric oxide binary composite material and aniline. The wave absorption properties of the corresponding ternary nanocomposite is regulated. The adjustment range of the content ratio of the reduced graphene oxide-ferric tetroxide binary composite material and aniline is 1:0.5-3. USE - Graphene-iron iron oxide-polyaniline ternary nanocomposite material with adjustable wave absorption properties. ADVANTAGE - The graphene-iron iron oxide-polyaniline ternary nanocomposite material with adjustable wave absorption properties is helps to the increase of the content of polyaniline, and gradually increases corresponding ternary nanocomposite material's absorbing strength. The width of the absorbing band has also increased significantly. It has wide application prospects in stealth materials, electromagnetic safety protection and other fields. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing a graphene-ferroferric oxide-polyaniline ternary nanocomposite material with adjustable wave absorbing properties, which involves: (A) dispersing 1-2.5 mole per liter ferric chloride and 0.5-1 mole per liter ferrous chloride ultrasonically in the graphene oxide aqueous dispersion, after fully mixed; (B) slowly adding 1-1.5 mole per liter ammonia water to maintain the pH at 10, after maintaining stirring for 1.5-3.5 hours; (C) adding 10-15 ml of hydrazine hydrate and using water/solvothermal or co-precipitation method at 80 to 120 degrees C for 4-6 hours; (D) centrifuging, washing, drying resulting product in vacuum, after grinding, and dotting graphene nano powder with ferroferric oxide particles; (E) taking 0.3-0.6g of reduced graphene oxide-ferroferric oxide binary composite nano-powder dispersed in 40-60ml of deionized water, slowly dissolving 2-20 gram dodecylbenzenesulfonic acid and 0.2-2g aniline; (F) keeping the temperature at (-)1-3 degrees C, ultrasonically stirring for 25-40 minutes; (G) adding 0.5-4 gram ammonium persulfate solution in deionized water, stirring for 4-5 hours, and then adding the same amount Isopropyl alcohol, and stirring for 20-40 minutes, then centrifuging and washing cuum drying to obtain graphene-ferroferric oxide-polyaniline ternary nano-composite absorbing materials; (H) changing the content ratio of the reduced graphene oxide-ferroferric oxide binary composite material and aniline; and (I) regulating the wave absorption properties of the corresponding ternary nanocomposite, where adjustment range of the content ratio of the reduced graphene oxide-ferric tetroxide binary composite material and aniline is 1:0.5-3.